CAJ | 학술논문

采用原位还原技术制备出Ni2P/TiO2-Al2O3催化剂，以喹啉为模型化合物对催化剂的加氢脱氮性能进行评价。主要考察复合载体中不同钛铝配比、不同Ni/P摩尔比对催化剂活性的影响及确定活性组分Ni2P负载量，确定该加氢脱氮催化剂最佳制备方法为：当n(Ti)/n(Al)=1/4，Ni2P负载量25%(wt)。在压力为3 MPa，体积空速为3 h-1，氢油体积比为500，反应温度为360℃的条件下，催化剂的加氢脱氮活性最高，可达98%。
채용원위환원기술제비출Ni2P/TiO2-Al2O3최화제，이규람위모형화합물대최화제적가경탈담성능진행평개。주요고찰복합재체중불동태려배비、불동Ni/P마이비대최화제활성적영향급학정활성조분Ni2P부재량，학정해가경탈담최화제최가제비방법위：당n(Ti)/n(Al)=1/4，Ni2P부재량25%(wt)。재압력위3 MPa，체적공속위3 h-1，경유체적비위500，반응온도위360℃적조건하，최화제적가경탈담활성최고，가체98%。
Ni2P/TiO2-Al2O3 catalyst was prepared by using in situ reduction technique. HDN properties of the catalyst were evaluated by using quinoline as model compound. The effects of Ti/Al ratio incomposite carrier, Ni/P molar ratio on the catalytic activity were investigated, and the loading of active component Ni2P was determined as well as the best preparation conditions.The results show that, when n (Ti)/n (Al) = 1/4, Ni2P load 25%(wt),pressure 3 MPa, volume 3 h-1, hydrogen/oil ratio 500, the reaction temperature 360 ℃,prepared catalyst has high hydrogenation denitrification activity.