当代化工
噹代化工
당대화공
CONTEMPORARY CHEMICAL INDUSTRY
2014年
5期
680-683,686
,共5页
李长波%赵国峥%邱峰%武腾
李長波%趙國崢%邱峰%武騰
리장파%조국쟁%구봉%무등
臭氧氧化%干法腈纶废水%预处理%后处理%可生化性%协同作用
臭氧氧化%榦法腈綸廢水%預處理%後處理%可生化性%協同作用
취양양화%간법정륜폐수%예처리%후처리%가생화성%협동작용
Ozone oxidation%Dry-spun acrylic fiber wastewater%Pretreatment%Post-treatment%Biodegradability%Synergistic reaction
将臭氧氧化法应用于干法腈纶废水中,通过实验考察了回流量、进气量以及针阀开度等对废水处理效果的影响。实验结果表明,当针阀完全打开,进气量为2 L/min,回流量为500 L/h时,处理效果最好,CODCr去除率可以达到28.5%,废水的可生化性也有所改善。对预处理和后处理两种方式对比研究表明,臭氧与H2O2联用后处理干法腈纶废水的效果明显好于预处理效果,也明显好于单独臭氧作用的处理效果,反应60 min后, CODCr可去除70.3%,CODCr降至80.59 mg/L。因此,臭氧氧化法尤其是臭氧与H2O2联用适合作为干法腈纶废水的后处理措施。
將臭氧氧化法應用于榦法腈綸廢水中,通過實驗攷察瞭迴流量、進氣量以及針閥開度等對廢水處理效果的影響。實驗結果錶明,噹針閥完全打開,進氣量為2 L/min,迴流量為500 L/h時,處理效果最好,CODCr去除率可以達到28.5%,廢水的可生化性也有所改善。對預處理和後處理兩種方式對比研究錶明,臭氧與H2O2聯用後處理榦法腈綸廢水的效果明顯好于預處理效果,也明顯好于單獨臭氧作用的處理效果,反應60 min後, CODCr可去除70.3%,CODCr降至80.59 mg/L。因此,臭氧氧化法尤其是臭氧與H2O2聯用適閤作為榦法腈綸廢水的後處理措施。
장취양양화법응용우간법정륜폐수중,통과실험고찰료회류량、진기량이급침벌개도등대폐수처리효과적영향。실험결과표명,당침벌완전타개,진기량위2 L/min,회류량위500 L/h시,처리효과최호,CODCr거제솔가이체도28.5%,폐수적가생화성야유소개선。대예처리화후처리량충방식대비연구표명,취양여H2O2련용후처리간법정륜폐수적효과명현호우예처리효과,야명현호우단독취양작용적처리효과,반응60 min후, CODCr가거제70.3%,CODCr강지80.59 mg/L。인차,취양양화법우기시취양여H2O2련용괄합작위간법정륜폐수적후처리조시。
The ozone oxidation process was used in dry-spun acrylic fiber wastewater treatment. The influences of back-flow, air input and degree of needle valve opening on the wastewater treatment efficiency were investigated. The experimental results show that, when the needle valve openes fully, the air input 2 L/min, the back-flow 500 L/h, the wastewater treatment efficiency is the best, the CODCr removal rate can reach 28.5%, and the wastewater biodegradability is also improved. The comparison research of pretreatment and post treatment shows that, the efficiency of ozone and H2O2 combination post-treatment is much better than pretreatment, and also much better than the treatment using ozone alone. When the reaction time is 60 min, 70.3%of CODCr can be removed, and the CODCr of effluent decreases to 80.59 mg/L. Therefore, the ozone oxidation process, especially the combination of ozone and H2O2, is suitable for the post treatment measure of dry-spun acrylic fiber wastewater.