广州化工
廣州化工
엄주화공
GUANGZHOU CHEMICAL INDUSTRY AND TECHNOLOGY
2012年
9期
135-136,140
,共3页
刘阳%周玄沐%乔彬彬%邓克俭
劉暘%週玄沐%喬彬彬%鄧剋儉
류양%주현목%교빈빈%산극검
手性%(R)-噻唑啉-4-羧酸%配合物%铁簇
手性%(R)-噻唑啉-4-羧痠%配閤物%鐵簇
수성%(R)-새서람-4-최산%배합물%철족
chiral%(R) - thiazolidine - 4 - carboxylic acid%complex%iron cluster
以与L-脯氨酸（L—Pro）拓扑同构的手性配体L一半胱胺酸衍生物Lcya-（R）-噻唑啉-4-羧酸，与Fe（Ⅲ）作用制得一种含金属簇Fe3O的手性配合物，通过x-射线单晶衍射测定并确认了其结构。
以與L-脯氨痠（L—Pro）拓撲同構的手性配體L一半胱胺痠衍生物Lcya-（R）-噻唑啉-4-羧痠，與Fe（Ⅲ）作用製得一種含金屬簇Fe3O的手性配閤物，通過x-射線單晶衍射測定併確認瞭其結構。
이여L-포안산（L—Pro）탁복동구적수성배체L일반광알산연생물Lcya-（R）-새서람-4-최산，여Fe（Ⅲ）작용제득일충함금속족Fe3O적수성배합물，통과x-사선단정연사측정병학인료기결구。
A novel chiral L - cysteine derivative （R） - thiazolidine - 4 - carboxylic acid, which had a similar topolo- gical isomorphism with L - proline （ L - Pro）, was successfully prepared by raw material. A chiral complex containing metal cluster of Fe3 0 was prepared by the chiral ligand and Fe （III） metal ion, and the accurate crystal structure of this complex was determined and confirmed by X -ray diffraction.
