合肥师范学院学报
閤肥師範學院學報
합비사범학원학보
JOURNAL OF ANHUI INSTITUTE OF EDUCATION
2012年
3期
80-83
,共4页
CuO/SnO2/TiO2纳米复合物%表征%制备%光催化性质
CuO/SnO2/TiO2納米複閤物%錶徵%製備%光催化性質
CuO/SnO2/TiO2납미복합물%표정%제비%광최화성질
CuO/SnO2/TiO2 nanocomposite%preparation%characterization%photocatalytic activity
采用溶胶-凝胶法,以硝酸铜、二氯化锡和钛酸四丁酯为原料,加入十六烷基三甲基溴化铵(CTAB)作软模板,制备CuO/Sn02/TiO2纳米复合物。分别用SEM、XRD、IR、UV—vis等对产物进行表征分析,CuO/SnO2/TiO2晶粒由锐钛矿相的TiO2、金红石相的SnO2和单斜晶系的CuO组成。以甲基橙为模拟污染物,研究其催化活性,结果表明CuO/SnO2/TiO2纳米复合物具有较好的光催化活性。
採用溶膠-凝膠法,以硝痠銅、二氯化錫和鈦痠四丁酯為原料,加入十六烷基三甲基溴化銨(CTAB)作軟模闆,製備CuO/Sn02/TiO2納米複閤物。分彆用SEM、XRD、IR、UV—vis等對產物進行錶徵分析,CuO/SnO2/TiO2晶粒由銳鈦礦相的TiO2、金紅石相的SnO2和單斜晶繫的CuO組成。以甲基橙為模擬汙染物,研究其催化活性,結果錶明CuO/SnO2/TiO2納米複閤物具有較好的光催化活性。
채용용효-응효법,이초산동、이록화석화태산사정지위원료,가입십륙완기삼갑기추화안(CTAB)작연모판,제비CuO/Sn02/TiO2납미복합물。분별용SEM、XRD、IR、UV—vis등대산물진행표정분석,CuO/SnO2/TiO2정립유예태광상적TiO2、금홍석상적SnO2화단사정계적CuO조성。이갑기등위모의오염물,연구기최화활성,결과표명CuO/SnO2/TiO2납미복합물구유교호적광최화활성。
The CuO/SnO2/TiO2 nanocomposite has been prepared by the sol--gel method, in which the CTAB was used as engaged-template that reacted with Cu(NO2 )2. SnCl2 andTi(OC4 H9)4. The nanocomposite as-obtained was characterized by SEM , XRD, IR and UV-vis. The CuO/SnO2/TiO2 nanocomposite was composed of anatase crystal TiO2 and rutile crystal SnO2 and monoclinic crystal CuO. Under sunlight the photocatalytic activity of CuO/SnO2/TiO2 nanocomposite as-obtained was studied by methyl orange as simulation pollutants. The CuO/SnO2/TiO2nanocomposite had excellent photocatalytic activity.