林产化学与工业
林產化學與工業
림산화학여공업
CHEMISTRY AND INDUSTRY OF FOREST PRODUCTS
2014年
2期
56-60
,共5页
麦草%复合有机酸%木质素%戊聚糖%黑液
麥草%複閤有機痠%木質素%戊聚糖%黑液
맥초%복합유궤산%목질소%무취당%흑액
wheat straw%complex organic acids%lignin%pentosan%black liquor
研究了麦草在甲酸-乙酸-水复合有机酸( FAWOA)体系中于常压反应条件下,反应温度和时间对麦草各组分溶出规律的影响。结果表明:麦草在与复合有机酸反应过程中,脱木质素历程可以分为3个阶段:大量脱木质素阶段,补充脱木质素阶段和残余脱木质素阶段,各阶段木质素溶出分别为37.1%、27.2%和2.50%;戊聚糖的反应历程也分为3个阶段:戊聚糖大量反应阶段、补充反应阶段和少量反应阶段,各阶段戊聚糖溶出分别为50.0%、24.9%和3.20%;综纤维素、苯-乙醇抽出物和灰分的溶出呈现与脱木质素、戊聚糖溶出相似的趋势;黑液中有机物含量的增加趋势与木质素和戊聚糖溶出趋势相似,而无机物含量变化很小,基本维持在2.0 g/L左右。
研究瞭麥草在甲痠-乙痠-水複閤有機痠( FAWOA)體繫中于常壓反應條件下,反應溫度和時間對麥草各組分溶齣規律的影響。結果錶明:麥草在與複閤有機痠反應過程中,脫木質素歷程可以分為3箇階段:大量脫木質素階段,補充脫木質素階段和殘餘脫木質素階段,各階段木質素溶齣分彆為37.1%、27.2%和2.50%;戊聚糖的反應歷程也分為3箇階段:戊聚糖大量反應階段、補充反應階段和少量反應階段,各階段戊聚糖溶齣分彆為50.0%、24.9%和3.20%;綜纖維素、苯-乙醇抽齣物和灰分的溶齣呈現與脫木質素、戊聚糖溶齣相似的趨勢;黑液中有機物含量的增加趨勢與木質素和戊聚糖溶齣趨勢相似,而無機物含量變化很小,基本維持在2.0 g/L左右。
연구료맥초재갑산-을산-수복합유궤산( FAWOA)체계중우상압반응조건하,반응온도화시간대맥초각조분용출규률적영향。결과표명:맥초재여복합유궤산반응과정중,탈목질소역정가이분위3개계단:대량탈목질소계단,보충탈목질소계단화잔여탈목질소계단,각계단목질소용출분별위37.1%、27.2%화2.50%;무취당적반응역정야분위3개계단:무취당대량반응계단、보충반응계단화소량반응계단,각계단무취당용출분별위50.0%、24.9%화3.20%;종섬유소、분-을순추출물화회분적용출정현여탈목질소、무취당용출상사적추세;흑액중유궤물함량적증가추세여목질소화무취당용출추세상사,이무궤물함량변화흔소,기본유지재2.0 g/L좌우。
Biorefinery process by organic acids is a potential way to utilize wheat straw effectively. The influences of reaction temperature and time on the dissolutions of the wheat straw chemical components in formic acid-acetic acid-water organic acids ( FAWOA) at atmospheric pressure were investigated in present study. The results indicated that the delignification process can be divided into three phases, namely a bulk phase, a complementary one and a residual one, with lignin removal by 37. 1%, 27.2% and 2. 50% respectively. The dissolution of pentosan also demonstrated as three stages, i. e. , a bulk one, a complementary one and a residual one, with the dissolution ratios of 50. 0%, 24. 9% and 3. 20% respectively. The removal of holocellulose, benzene-ethanol and ash can be divided into similar three phases as the removal of lignin and pentosan. The increasing trend of organic matter content in black liquor was similar to that of lignin and pentosan. However, only a slight variation of inorganic matter content was observed and represented a constant level at 2. 0 g/L in the biorefinery process.