CAJ | 학술논문

采用锥形量热法研究了5A分子筛与聚磷酸铵(APP)在木材燃烧过程中的阻燃作用和烟气吸附调控作用。结果表明：APP单独使用时总热释放量( THR)降低47.56%,但是平均CO产率增加185.71%；5A分子筛单独使用时阻燃效果远远不如APP,THR只降低了16.86%；5A分子筛与APP复合使用THR降低34.23%,总烟释放量(TSP)降低了76.07%,平均CO产率降低了68.33%。5A分子筛能将木材热解产生的以CO为代表的有毒气体催化转化为CO2,从而减少了毒气的产生和释放。5A分子筛与APP联用,在高效阻燃的同时减少烟雾毒气释放,降低了火灾危害。
채용추형량열법연구료5A분자사여취린산안(APP)재목재연소과정중적조연작용화연기흡부조공작용。결과표명：APP단독사용시총열석방량( THR)강저47.56%,단시평균CO산솔증가185.71%；5A분자사단독사용시조연효과원원불여APP,THR지강저료16.86%；5A분자사여APP복합사용THR강저34.23%,총연석방량(TSP)강저료76.07%,평균CO산솔강저료68.33%。5A분자사능장목재열해산생적이CO위대표적유독기체최화전화위CO2,종이감소료독기적산생화석방。5A분자사여APP련용,재고효조연적동시감소연무독기석방,강저료화재위해。
The effect of molecular sieve 5A and ammonium polyphosphate ( APP) on the flame retardance and smoking-gas absorption in wood during the combustion process was investigated by cone calorimeter. The results showed that when APP was used as sole flame retardant, the total heat release (THR) reduced by 47. 56% while mean yield of CO (mean-COY) increased by 185. 71 %. The application of molecular sieve 5A was found to have an inferior flame retardant efficiency. THR decreased by 16. 86 % through it. However, when 5A molecular sieve and APP was combined and used as flame retardant for wood, THR, total smoke production (TSP) and mean-COY reduced by 34. 23%, 76. 07% and 68. 33%, respectively. CO, a representative toxic, was converted into CO2 by the use of 5A molecular sieve as catalyst. Thus the generation and release of toxic gas reduced. In short, high efficiency of flame retardance and smoke suppression in wood can be achieved when the flame retardants of 5A molecular sieve and APP were coused together. Thus the casualties in the fire were reduced.