光谱学与光谱分析
光譜學與光譜分析
광보학여광보분석
SPECTROSCOPY AND SPECTRAL ANALYSIS
2014年
4期
919-921
,共3页
董丽芳%仝国良%张玉%周斌
董麗芳%仝國良%張玉%週斌
동려방%동국량%장옥%주빈
大面积沿面放电%振动温度%电子激发温度
大麵積沿麵放電%振動溫度%電子激髮溫度
대면적연면방전%진동온도%전자격발온도
Large area surface discharge%Vibrational temperature%Electronic excitation temperature
设计了水电极放电装置,在空气/氩气混合气体中实现了大面积沿面放电。采用发射光谱法,对分子振动温度、电子平均能量和电子激发温度等随气压的变化进行了研究。根据氮分子第二正带系( C3Πu → B 3Πg )的发射谱线计算出氮分子的振动温度;使用A r 763.51 nm (2 P6→1 S5)和772.42 nm (2 P2→1 S3)的两条发射谱线的强度比得到电子激发温度;通过氮分子离子391.4 nm和氮分子337.1 nm两条发射谱线的相对强度之比得出了电子的平均能量的变化。实验研究了发射光谱随气压的变化,发现其强度随着气压的增加而增强,且其整个轮廓和谱线强度之比也发生变化。随着气压从0.75×105 Pa升高到1×105 Pa ,分子振动温度、电子激发温度和电子能量均呈下降趋势。
設計瞭水電極放電裝置,在空氣/氬氣混閤氣體中實現瞭大麵積沿麵放電。採用髮射光譜法,對分子振動溫度、電子平均能量和電子激髮溫度等隨氣壓的變化進行瞭研究。根據氮分子第二正帶繫( C3Πu → B 3Πg )的髮射譜線計算齣氮分子的振動溫度;使用A r 763.51 nm (2 P6→1 S5)和772.42 nm (2 P2→1 S3)的兩條髮射譜線的彊度比得到電子激髮溫度;通過氮分子離子391.4 nm和氮分子337.1 nm兩條髮射譜線的相對彊度之比得齣瞭電子的平均能量的變化。實驗研究瞭髮射光譜隨氣壓的變化,髮現其彊度隨著氣壓的增加而增彊,且其整箇輪廓和譜線彊度之比也髮生變化。隨著氣壓從0.75×105 Pa升高到1×105 Pa ,分子振動溫度、電子激髮溫度和電子能量均呈下降趨勢。
설계료수전겁방전장치,재공기/아기혼합기체중실현료대면적연면방전。채용발사광보법,대분자진동온도、전자평균능량화전자격발온도등수기압적변화진행료연구。근거담분자제이정대계( C3Πu → B 3Πg )적발사보선계산출담분자적진동온도;사용A r 763.51 nm (2 P6→1 S5)화772.42 nm (2 P2→1 S3)적량조발사보선적강도비득도전자격발온도;통과담분자리자391.4 nm화담분자337.1 nm량조발사보선적상대강도지비득출료전자적평균능량적변화。실험연구료발사광보수기압적변화,발현기강도수착기압적증가이증강,차기정개륜곽화보선강도지비야발생변화。수착기압종0.75×105 Pa승고도1×105 Pa ,분자진동온도、전자격발온도화전자능량균정하강추세。
A large area surface discharge was realized in air/argon gas mixture by designing a discharge device with water elec-trodes .By using optical emission spectrum ,the variations of the molecular vibrational temperature ,the mean energy of electron , and the electronic excitation temperature as a function of the gas pressure were studied .The nitrogen molecular vibrational tem-perature was calculated according to the emission line of the second positive band system of the nitrogen molecule (C 3Πu → B 3Πg ). The electronic excitation temperature was obtained by using the intensity ratio of Ar Ⅰ 763.51 nm(2 P6 →1S5 ) to Ar Ⅰ772.42 nm (2P2 →1S3). The changes in the mean energy of electron were studied by the relative intensity ratio of the nitrogen molecular ion 391.4 nm to nitrogen 337.1 nm .It was found that the intensity of emission spectral line increases with the increase in the gas pressure ,meanwhile ,the outline and the ratios of different spectral lines intensity also change .The molecular vibra-tional temperature ,the mean energy of electron ,and the electronic excitation temperature decrease as the gas pressure increases from 0.75 × 105 Pa to 1 × 105 Pa.