光谱学与光谱分析
光譜學與光譜分析
광보학여광보분석
SPECTROSCOPY AND SPECTRAL ANALYSIS
2014年
4期
884-887
,共4页
朱永乐%王淑英%刘静%仲崇玉%阿布都艾尼·由力瓦斯%戴康%沈异凡
硃永樂%王淑英%劉靜%仲崇玉%阿佈都艾尼·由力瓦斯%戴康%瀋異凡
주영악%왕숙영%류정%중숭옥%아포도애니·유력와사%대강%침이범
激光光谱%碰撞能量转移%预解离%时间分辨荧光%NaK (61Σ+ )- H2
激光光譜%踫撞能量轉移%預解離%時間分辨熒光%NaK (61Σ+ )- H2
격광광보%팽당능량전이%예해리%시간분변형광%NaK (61Σ+ )- H2
Laser spectroscopy%Collisional energy transfer%Predissociation%Time resolved fluorescence%NaK(61Σ+ )+ H2
脉冲激光激发NaK 21Σ+←11Σ+跃迁,单模Ti宝石激光器激发21Σ+至高位态61Σ+,研究了61Σ+与H2碰撞中的碰撞转移。3 D→4 P(1.7μm )和5 S→4 P(1.24μm )荧光发射说明了预解离和碰撞解离的产生。在不同的H2密度下,通过以上能级的荧光测量得到了预解离率,碰撞解离及碰撞转移速率系数ΓP3D =(5.3±2.5)×108 s-1,ΓP5S =(3.1±1.5)×108 s-1,k3D =(3.7±1.7)×10-11 cm3· s-1,k5S =(2.9±1.4)×10-11 cm3· s-1,k4P→4S=(1.1±0.5)×10-11 cm3· s-1,k3D→4P=(6.5±3.1)×10-12 cm3· s-1,k5S→4P=(4.1±1.9)×10-12 cm3· s-1。在不同 H2密度下,记录时间分辨荧光,由Stern-Volmer公式得到61Σ+→21Σ+,21Σ+→11Σ+的自发辐射寿命分别为(28±10) ns和(15±4) ns。61Σ+→21Σ+,61Σ+→11Σ+及21Σ+→11Σ+分子态间与H2的碰撞转移速率系数分别为(1.8±0.6)×10-11 cm3· s-1,(1.6±0.5)×10-10 cm3· s-1和(6.3±1.9)×10-11 cm3· s-1。转移到H2的振动、转动和平动能各占总转移能的0.58,0.03和0.39。主要能量转移至振动和平动能,支持61Σ+- H2间的共线型碰撞机制。
脈遲激光激髮NaK 21Σ+←11Σ+躍遷,單模Ti寶石激光器激髮21Σ+至高位態61Σ+,研究瞭61Σ+與H2踫撞中的踫撞轉移。3 D→4 P(1.7μm )和5 S→4 P(1.24μm )熒光髮射說明瞭預解離和踫撞解離的產生。在不同的H2密度下,通過以上能級的熒光測量得到瞭預解離率,踫撞解離及踫撞轉移速率繫數ΓP3D =(5.3±2.5)×108 s-1,ΓP5S =(3.1±1.5)×108 s-1,k3D =(3.7±1.7)×10-11 cm3· s-1,k5S =(2.9±1.4)×10-11 cm3· s-1,k4P→4S=(1.1±0.5)×10-11 cm3· s-1,k3D→4P=(6.5±3.1)×10-12 cm3· s-1,k5S→4P=(4.1±1.9)×10-12 cm3· s-1。在不同 H2密度下,記錄時間分辨熒光,由Stern-Volmer公式得到61Σ+→21Σ+,21Σ+→11Σ+的自髮輻射壽命分彆為(28±10) ns和(15±4) ns。61Σ+→21Σ+,61Σ+→11Σ+及21Σ+→11Σ+分子態間與H2的踫撞轉移速率繫數分彆為(1.8±0.6)×10-11 cm3· s-1,(1.6±0.5)×10-10 cm3· s-1和(6.3±1.9)×10-11 cm3· s-1。轉移到H2的振動、轉動和平動能各佔總轉移能的0.58,0.03和0.39。主要能量轉移至振動和平動能,支持61Σ+- H2間的共線型踫撞機製。
맥충격광격발NaK 21Σ+←11Σ+약천,단모Ti보석격광기격발21Σ+지고위태61Σ+,연구료61Σ+여H2팽당중적팽당전이。3 D→4 P(1.7μm )화5 S→4 P(1.24μm )형광발사설명료예해리화팽당해리적산생。재불동적H2밀도하,통과이상능급적형광측량득도료예해리솔,팽당해리급팽당전이속솔계수ΓP3D =(5.3±2.5)×108 s-1,ΓP5S =(3.1±1.5)×108 s-1,k3D =(3.7±1.7)×10-11 cm3· s-1,k5S =(2.9±1.4)×10-11 cm3· s-1,k4P→4S=(1.1±0.5)×10-11 cm3· s-1,k3D→4P=(6.5±3.1)×10-12 cm3· s-1,k5S→4P=(4.1±1.9)×10-12 cm3· s-1。재불동 H2밀도하,기록시간분변형광,유Stern-Volmer공식득도61Σ+→21Σ+,21Σ+→11Σ+적자발복사수명분별위(28±10) ns화(15±4) ns。61Σ+→21Σ+,61Σ+→11Σ+급21Σ+→11Σ+분자태간여H2적팽당전이속솔계수분별위(1.8±0.6)×10-11 cm3· s-1,(1.6±0.5)×10-10 cm3· s-1화(6.3±1.9)×10-11 cm3· s-1。전이도H2적진동、전동화평동능각점총전이능적0.58,0.03화0.39。주요능량전이지진동화평동능,지지61Σ+- H2간적공선형팽당궤제。
The radiative lifetimes and rate coefficients for deactivation of high lying 61Σ+ state of NaK by collisions with H2 were studied .An OPO laser was set to a particular 21Σ+ ←11Σ+ transition .Another single mode Ti sapphire laser was then used to excite molecule from 21Σ+ level to the 61Σ+ state .The predissociation was monitored by the atomic potassium emission at the 3D→4P (1.7 μm) or the S→4P(1.24μm) ,while bound state radiative processes were monitored by total fluorescence from the upper state to the various levels ,all studied as a function of H2 density .The values for predissociation ,collisional dissociation and collisional depopulation rate coefficients were obtained .The decay signal of the time resolved fluorescence from the 61Σ+ →21Σ+ ,61Σ+ →11Σ+ or 21Σ+ →11Σ+ transition was monitored .Based on the Stern-Volmer equation ,the radiative lifetimes were monitored for 61Σ+ →21Σ+ and 21Σ+ →11Σ+ transition .The rate coefficients for deactivation of collisions with H 2 were moni-tored for 61Σ+ →21Σ+ ,61Σ+ →11Σ+ and 21Σ+ →11Σ+ .When the density of H2 was 1019 cm -3 ,the total collisional transfer en-ergy (15 426 cm-1 ) and radiative energy (10 215 cm -1 ) were obtained .The relative fraction (<fv> ,<fR> ,<fT>) of average en-ergy disposal was derived as (0.58 ,0.03 ,0.39);<fv> ,<fR> ,<fT> represent separately the relative fraction of average energy disposal among vibration ,rotation and translation .The major vibrational and translational energy release supports the assump-tion that the 61Σ+-H2 collision occurs primarily in a collisional energy transfer mechanism .In this experiment ,alkali molecules relative energy population ratio was determined through using the time integrated intensity ,so we can get the total transfer ener-gy .That the NaK (61Σ+ ) energy transfers to the H2 vibrational ,rotational and translational energy was quantitatively given for the first time ,which illustrates the collisional mechanism .