浙江海洋学院学报:自然科学版
浙江海洋學院學報:自然科學版
절강해양학원학보:자연과학판
Journal of Zhejiang Ocean University(Natural Science Edition)
2012年
2期
153-156
,共4页
原子吸收光谱法%锂含量%浓海水%标准加入法
原子吸收光譜法%鋰含量%濃海水%標準加入法
원자흡수광보법%리함량%농해수%표준가입법
atomic absorption spectrometry%lithium content%concentrated brine%standard addition method
采用空气-乙炔火焰原子吸收光谱法测定浓海水中微量金属锂离子时,干扰主要来自浓海水中共存的高浓度的阳离子。探讨了共存的主要阳离子对锂离子测定的影响,并分析了消除高浓度阳离子干扰的方法。结果表明:Ca2+和Mg2+是主要干扰元素,可以采用标准加入法消除共存的高浓度阳离子的干扰;锂在0.13~1.92 mg/L范围内线性关系良好,平均回收率为99.62%。
採用空氣-乙炔火燄原子吸收光譜法測定濃海水中微量金屬鋰離子時,榦擾主要來自濃海水中共存的高濃度的暘離子。探討瞭共存的主要暘離子對鋰離子測定的影響,併分析瞭消除高濃度暘離子榦擾的方法。結果錶明:Ca2+和Mg2+是主要榦擾元素,可以採用標準加入法消除共存的高濃度暘離子的榦擾;鋰在0.13~1.92 mg/L範圍內線性關繫良好,平均迴收率為99.62%。
채용공기-을결화염원자흡수광보법측정농해수중미량금속리리자시,간우주요래자농해수중공존적고농도적양리자。탐토료공존적주요양리자대리리자측정적영향,병분석료소제고농도양리자간우적방법。결과표명:Ca2+화Mg2+시주요간우원소,가이채용표준가입법소제공존적고농도양리자적간우;리재0.13~1.92 mg/L범위내선성관계량호,평균회수솔위99.62%。
The trace Li^+ in concentrated brine was determined by air-acetylene flame atomic absorption spectrometry at the wave length of 670.8 nm. The disturbance from coexisting cations on the lithium (1+) was investigated. The disturbance was from high concentration ions of Ca^2+ and Mg^2+. The ions of Na^+ and K^+ had little affection. The standard addition method is an effective way to eliminate the disturbance of main cations. The experimental results indicated that the linear range for lithium was 0.13-1.92 mg/L and average recovery was 99.62%.