莆田学院学报
莆田學院學報
보전학원학보
JOURNAL OF PUTIAN UNIVERISTY
2012年
2期
86-89
,共4页
蔡力锋%郑炳云%傅明连%蔡丽芳
蔡力鋒%鄭炳雲%傅明連%蔡麗芳
채력봉%정병운%부명련%채려방
埃洛石纳米管%硅烷%表面修饰%次甲基蓝%吸附
埃洛石納米管%硅烷%錶麵脩飾%次甲基藍%吸附
애락석납미관%규완%표면수식%차갑기람%흡부
HNTs%silane%surface modification%methylene blue%adsorption
采用硅烷偶联剂对埃洛石纳米管(HNTs)进行表面修饰,通过透射电子显微镜(TEM)、红外光谱仪(FTIR)、分光光度计等对HNTs的结构和吸附性能进行了表征。结果表明,硅烷偶联剂通过化学键实现了对HNTs的表面修饰,提高了HNTs在溶液中的分散稳定性;适当提高溶液温度、延长吸附时间及增加溶液pH值有助于提高HNTs对次甲基蓝的吸附量。当溶液温度为303K,吸附时间为90min,溶液pH值为7时,表面修饰HNTs的吸附量可达8.91mg/g,相对于表面未修饰HNTs(同等条件下的吸附量为7.83mg/g)明显提高。吸附后的表面修饰HNTs经过再生处理后,吸附量可达到7.66mg/g。
採用硅烷偶聯劑對埃洛石納米管(HNTs)進行錶麵脩飾,通過透射電子顯微鏡(TEM)、紅外光譜儀(FTIR)、分光光度計等對HNTs的結構和吸附性能進行瞭錶徵。結果錶明,硅烷偶聯劑通過化學鍵實現瞭對HNTs的錶麵脩飾,提高瞭HNTs在溶液中的分散穩定性;適噹提高溶液溫度、延長吸附時間及增加溶液pH值有助于提高HNTs對次甲基藍的吸附量。噹溶液溫度為303K,吸附時間為90min,溶液pH值為7時,錶麵脩飾HNTs的吸附量可達8.91mg/g,相對于錶麵未脩飾HNTs(同等條件下的吸附量為7.83mg/g)明顯提高。吸附後的錶麵脩飾HNTs經過再生處理後,吸附量可達到7.66mg/g。
채용규완우련제대애락석납미관(HNTs)진행표면수식,통과투사전자현미경(TEM)、홍외광보의(FTIR)、분광광도계등대HNTs적결구화흡부성능진행료표정。결과표명,규완우련제통과화학건실현료대HNTs적표면수식,제고료HNTs재용액중적분산은정성;괄당제고용액온도、연장흡부시간급증가용액pH치유조우제고HNTs대차갑기람적흡부량。당용액온도위303K,흡부시간위90min,용액pH치위7시,표면수식HNTs적흡부량가체8.91mg/g,상대우표면미수식HNTs(동등조건하적흡부량위7.83mg/g)명현제고。흡부후적표면수식HNTs경과재생처리후,흡부량가체도7.66mg/g。
Halloysite nanotubes(HNTs) were modified with silane coupling agent.The structure and adsorption properties of HNTs were characterized by TEM,FTIR,spectrophotometer,etc.Results show that silane is chemically bonded onto HNTs,lead to the improved dispersion stability of HNTs in solution.Increases temperature,prolongs adsorption time,and elevates pH value,results in the improvement of HNTs' adsorption capacity on methylene blue.When the temperature is 303 K,adsorption time is 90 min,and the pH value is 7,the adsorption capacity of the modified HNTs is about 8.91 mg/g,which is higher than that of the unmodified ones(7.83 mg/g,under the same condition).After regeneration,the adsorption capacity of the adsorbed modified HNTs is able to reach 7.66 mg/g.