广西民族大学学报:自然科学版
廣西民族大學學報:自然科學版
엄서민족대학학보:자연과학판
Journal of Guangxi University For Nationalities(Natural Science Edition)
2012年
1期
84-87
,共4页
王代银%罗伟强%汤金牛%安永鹏
王代銀%囉偉彊%湯金牛%安永鵬
왕대은%라위강%탕금우%안영붕
晶体结构%氟康唑%锌%配位聚合物
晶體結構%氟康唑%鋅%配位聚閤物
정체결구%불강서%자%배위취합물
crystal structure%fluconazole%Zinc%coordination polymer
用水热合成法以硝酸锌、氟康唑(HFlu)、甲酸为原料合成了一种新颖的配合物,利用单晶X射线、元素分析、等对配合物进行了表征.单晶X射线衍射分析的结果表明:标题化合物属于三斜晶系,空间群为P-1,晶胞参数为a=10.503(10),b=11.745(11),c=14.122(13),α=90.808(11),β=105.841(11),γ=101.996(11).锌采用六配位的模式,且位于变形的八面体中心,每个锌原子分别与4个各异氟康唑上的三氮唑[Zn-N=2,156(2)]的4-号氮原子以及两个甲酸根[Zn-O=2.086(2)或者是2.137(5)]进行配位.
用水熱閤成法以硝痠鋅、氟康唑(HFlu)、甲痠為原料閤成瞭一種新穎的配閤物,利用單晶X射線、元素分析、等對配閤物進行瞭錶徵.單晶X射線衍射分析的結果錶明:標題化閤物屬于三斜晶繫,空間群為P-1,晶胞參數為a=10.503(10),b=11.745(11),c=14.122(13),α=90.808(11),β=105.841(11),γ=101.996(11).鋅採用六配位的模式,且位于變形的八麵體中心,每箇鋅原子分彆與4箇各異氟康唑上的三氮唑[Zn-N=2,156(2)]的4-號氮原子以及兩箇甲痠根[Zn-O=2.086(2)或者是2.137(5)]進行配位.
용수열합성법이초산자、불강서(HFlu)、갑산위원료합성료일충신영적배합물,이용단정X사선、원소분석、등대배합물진행료표정.단정X사선연사분석적결과표명:표제화합물속우삼사정계,공간군위P-1,정포삼수위a=10.503(10),b=11.745(11),c=14.122(13),α=90.808(11),β=105.841(11),γ=101.996(11).자채용륙배위적모식,차위우변형적팔면체중심,매개자원자분별여4개각이불강서상적삼담서[Zn-N=2,156(2)]적4-호담원자이급량개갑산근[Zn-O=2.086(2)혹자시2.137(5)]진행배위.
A coordination polymer containing divalent zinc,fluconazole,formic acid radical has been obtained by hydrothermal method.Its structure was determined by means of single-crystal X-ray diffraction analysis with the following crystal data:triclinic space group P-1,a = 10.503(10) ,b = 11.745(11) ,c= 14.122(13) ,α= 90.808(11) ,β= 105.841(11) ,γ= 101.996(11) .The mode of Zinc was Six coordination and located the center of distortion octahedral,Each zinc center was coordinated to four triazole nitrogen[Zn-N=2,156(2) ] atoms from distinct fluconazole ligands and a pair of formic acid radical[Zn-O=2.086(2) or.137(5) ].