功能材料
功能材料
공능재료
JOURNAL OF FUNCTIONAL MATERIALS
2013年
19期
2810-2813,2818
,共5页
袁美蓉%赵方辉%刘伟强%朱永法%王臣
袁美蓉%趙方輝%劉偉彊%硃永法%王臣
원미용%조방휘%류위강%주영법%왕신
超级电容器%石墨烯%氧化还原法%比电容%循环伏安法
超級電容器%石墨烯%氧化還原法%比電容%循環伏安法
초급전용기%석묵희%양화환원법%비전용%순배복안법
supercapacitor%graphene%redox method%specific capacitance%cyclic voltammetry
以石墨粉为原料,通过简便的氧化还原法制备了石墨烯。将石墨烯极片在有机电解液体系中组装成超级电容器。利用 XRD、SEM 对制备的石墨烯电极进行物相和形貌分析。采用恒电流充放电、循环伏安和交流阻抗对所制备超级电容器的电容性能进行了研究。结果表明,石墨烯电极超级电容器比天然石墨制备的超级电容器的比电容有了明显的提高;在电流密度为200mA/g,电压区间为1.25~2.5V 下循环888次后比电容保持在45.5F/g,容量保持率在85.5%,表明石墨烯材料制备的电容器具有较好的充放电循环性能。
以石墨粉為原料,通過簡便的氧化還原法製備瞭石墨烯。將石墨烯極片在有機電解液體繫中組裝成超級電容器。利用 XRD、SEM 對製備的石墨烯電極進行物相和形貌分析。採用恆電流充放電、循環伏安和交流阻抗對所製備超級電容器的電容性能進行瞭研究。結果錶明,石墨烯電極超級電容器比天然石墨製備的超級電容器的比電容有瞭明顯的提高;在電流密度為200mA/g,電壓區間為1.25~2.5V 下循環888次後比電容保持在45.5F/g,容量保持率在85.5%,錶明石墨烯材料製備的電容器具有較好的充放電循環性能。
이석묵분위원료,통과간편적양화환원법제비료석묵희。장석묵희겁편재유궤전해액체계중조장성초급전용기。이용 XRD、SEM 대제비적석묵희전겁진행물상화형모분석。채용항전류충방전、순배복안화교류조항대소제비초급전용기적전용성능진행료연구。결과표명,석묵희전겁초급전용기비천연석묵제비적초급전용기적비전용유료명현적제고;재전류밀도위200mA/g,전압구간위1.25~2.5V 하순배888차후비전용보지재45.5F/g,용량보지솔재85.5%,표명석묵희재료제비적전용기구유교호적충방전순배성능。
Graphene were prepared by simple redox method using graphite as raw materials.Supercapacitors were fabricated using the as-prepared graphene as electrode in organic electrolyte .The phase and morphology were characterized by XRD and SEM methods.The performance of supercapacitors were analyzed using gal-vanostatic charging and discharging testing,cyclic voltammetry and electrochemical impedance spectroscopy. The results showed that graphene-based supercapacitors had larger values of specific capacitance than that of the natural graphite-based ones.The specific capacitance was 45.5F/g (rentention rate at 85.5%)after 888 char-ging and discharging cycles at the current density of 200mA/g between the voltage from 1.25 to 2.5V.The gra-phene-based supercapacitors have a good charge-discharge cycle performance.