CAJ | 학술논문

以十二烷基三甲基氯化铵、四丁基溴化铵为相转移催化剂，以丙二醇等组分为稳定剂，以30％盐酸等组分为pH词节剂，在充入N2和CO2使釜压达0．1-0．12MPa条件下，将γ-氯丙基三甲氧基硅烷以及NaHS溶液分别打入反应釜进行合成反应。反应液经分层、脱色、蒸馏等工序获γ-巯丙基三甲氧基硅烷。该工艺具有反应温度低、反应时间短、产品纯度高达98．5％（优级品99％以上）、质量稳定、综合成本低等优点，有较好的应用价值和工业化前景。
이십이완기삼갑기록화안、사정기추화안위상전이최화제，이병이순등조분위은정제，이30％염산등조분위pH사절제，재충입N2화CO2사부압체0．1-0．12MPa조건하，장γ-록병기삼갑양기규완이급NaHS용액분별타입반응부진행합성반응。반응액경분층、탈색、증류등공서획γ-구병기삼갑양기규완。해공예구유반응온도저、반응시간단、산품순도고체98．5％（우급품99％이상）、질량은정、종합성본저등우점，유교호적응용개치화공업화전경。
With laurtrimonium chloride and tetrabutyl ammonium bromide as phase transfer catalysts, with propylene glycol etc. as stabilizing agent, with 30% hydrochloric acid as pH regulator, under the condition of reactor inside pressure which reached 0.1- 0.2MPa by the addition of N2 and CO2, γ- mercaptopropyltrimethoxysilane was obtained through the course of synthesis which γ - chloropropyltrichlorosilane reacted with sodium bisulfide solution in reactor, lay separation, decolorizafion, distillation. The technology had the advantages of low reaction temperature, short reaction time, high purity which was up to 98.5 percent （ super product was above 99 percent）, stable quanlity, lowr comprehensive cost, and had a good application value and a good industrial prospects.