无机化学学报
無機化學學報
무궤화학학보
JOURNAL OF INORGANIC CHEMISTRY
2008年
8期
1347-1351
,共5页
肖杰%赵玉媛%王文祥%赵红
肖傑%趙玉媛%王文祥%趙紅
초걸%조옥원%왕문상%조홍
锌配合物%水热合成%晶体结构%荧光性质
鋅配閤物%水熱閤成%晶體結構%熒光性質
자배합물%수열합성%정체결구%형광성질
zinc complex%hydrothennal synthesis%crystal structure%fluorescence
A zinc(Ⅱ) complex [(5-(4-nitrophenyl)tetrazolato)2Zn]n was obtained by the hydrothermal treatment of ZnBr2 and NaN3 with 4-nitrobenzonitril in water at 120 ℃ in Pyrex tube. The crystal belongs to orthorhombic system with space group Pbcn, and a=1.0407(5) nm, b=1.382 1(7) nm, c=2.435 l(13) nm, V=3.503(3) nm3, Z=8.This complex is a good blue fluorescent material in solid state at room temperature. CCDC: 684226.
