绝缘材料
絕緣材料
절연재료
INSULATING MATERIALS
2014年
1期
44-47,51
,共5页
酚醛环氧树脂%固化反应%热性能%粘结性能
酚醛環氧樹脂%固化反應%熱性能%粘結性能
분철배양수지%고화반응%열성능%점결성능
phenolic epoxy resin%curing reaction%heat resistance%adhesion
为了解特种酚醛型环氧树脂的应用特性，通过选取双酚A型、溴化苯酚型、联苯型及三酚型4种特种酚醛型环氧树脂，采用线型酚醛作固化剂，分析了树脂体系的固化反应特性及其覆铜板的耐热性、力学性能与粘结性能。结果表明：联苯型酚醛环氧的反应速度最慢，固化时需较高的温度，制成的覆铜板具有最高的热分解温度、弯曲储能模量与粘结性能，但其玻璃化转变温度却最低；三酚型酚醛环氧树脂具较高的玻璃化转变温度，但失重1%与2%时的热分解温度都最低。
為瞭解特種酚醛型環氧樹脂的應用特性，通過選取雙酚A型、溴化苯酚型、聯苯型及三酚型4種特種酚醛型環氧樹脂，採用線型酚醛作固化劑，分析瞭樹脂體繫的固化反應特性及其覆銅闆的耐熱性、力學性能與粘結性能。結果錶明：聯苯型酚醛環氧的反應速度最慢，固化時需較高的溫度，製成的覆銅闆具有最高的熱分解溫度、彎麯儲能模量與粘結性能，但其玻璃化轉變溫度卻最低；三酚型酚醛環氧樹脂具較高的玻璃化轉變溫度，但失重1%與2%時的熱分解溫度都最低。
위료해특충분철형배양수지적응용특성，통과선취쌍분A형、추화분분형、련분형급삼분형4충특충분철형배양수지，채용선형분철작고화제，분석료수지체계적고화반응특성급기복동판적내열성、역학성능여점결성능。결과표명：련분형분철배양적반응속도최만，고화시수교고적온도，제성적복동판구유최고적열분해온도、만곡저능모량여점결성능，단기파리화전변온도각최저；삼분형분철배양수지구교고적파리화전변온도，단실중1%여2%시적열분해온도도최저。
To investigate the application characteristic of special phenolic epoxy resin, using phenolic res-in as curing agent, the curing reaction characteristic of bisphenol A type, brominated phenol type, bi-phe-nyl type and tri-phenol type phenolic epoxy resin and the heat-resistance, mechanical properties and adhe-sion of the copper clad laminate were studied. The results show that the bi-phenyl type phenolic epoxy resin has the slowest reaction speed and requires higher curing temperature, the prepared laminate has the highest thermal decomposition temperature, bending storage modulus and adhesion, but the glass transition temperature shows the lowest. The tri-phenol type phenolic epoxy resin has a higher glass transition tem-perature, but its thermal decomposition temperature at 1% and 2% weight loss shows the lowest.
