CAJ | 학술논문

采用固相烧结法,以LiOH、FeC2O4.2H2O、Nb2O5、正硅酸四乙酯和蔗糖为原料制备出单斜结构的Li2.05FexNb2（1-x）/3SiO4/C（x=1,0.99,0.98,0.96,0.94,0.92,0.90）系列样品.通过红外光谱、X射线衍射、扫描电镜、恒电流充放电测试、交流阻抗和循环伏安法等方法研究了制备样品的结构及电化学性能.实验结果表明,颗粒尺寸介于0.2～1.5μm之间的Li2.05Fe0.96Nb0.026 7SiO4/C的充放电性能最好,在0.3C倍率电流下,第1次循环的放电容量为116.6 mAh/g,第30循环的放电容量为78.3 mAh/g.掺铌减少了样品的电荷传递阻抗,提高了锂离子的扩散系数.
채용고상소결법,이LiOH、FeC2O4.2H2O、Nb2O5、정규산사을지화자당위원료제비출단사결구적Li2.05FexNb2（1-x）/3SiO4/C（x=1,0.99,0.98,0.96,0.94,0.92,0.90）계렬양품.통과홍외광보、X사선연사、소묘전경、항전류충방전측시、교류조항화순배복안법등방법연구료제비양품적결구급전화학성능.실험결과표명,과립척촌개우0.2～1.5μm지간적Li2.05Fe0.96Nb0.026 7SiO4/C적충방전성능최호,재0.3C배솔전류하,제1차순배적방전용량위116.6 mAh/g,제30순배적방전용량위78.3 mAh/g.참니감소료양품적전하전체조항,제고료리리자적확산계수.
Li2.05FexNb2（1-x）/3SiO4/C（x=1,0.99,0.98,0.96,0.94,0.92,0.90）were prepared by the solid reaction of LiOHoH2O,FeC2O4o2H2O,C8H20OSi,Nb2O5 and sugar.The prepared samples were characterized by the FTIR,XRD,SEM,charge-discharge cycle,electrochemical impedance and cyclic voltammogram.The experimental results show that Li2.05Fe0.96Nb0.0267SiO4/C with the particle-size of 0.2-1.5 μm exhibits the best charge-discharge performance in the as-prepared samples,which exhibits a capacity 116.6 mAh/g in the 1st cycle and 78.3 mAh/g in the 30th cycle.The niobium doping reduces charge transfer impedance,and increases the lithium-ion diffusion coefficient than that of undoped sample.