南京师范大学学报:工程技术版
南京師範大學學報:工程技術版
남경사범대학학보:공정기술판
Journal of Nanjing Nor Univ: Eng and Technol
2012年
3期
80-84
,共5页
吸水树脂%引发剂%吸收%交联剂%保水性
吸水樹脂%引髮劑%吸收%交聯劑%保水性
흡수수지%인발제%흡수%교련제%보수성
water absorbent resin%initiator%adsorption%crosslinker%water retention
以废弃聚乙烯(PE)塑料与丙烯酸(AA)及其盐为原料,采用微波加热法接枝共聚合成一种吸水树脂.研究了引发剂用量、交联剂种类、AA中和度对树脂吸水率的影响,发现当引发剂用量为单体的4%、交联剂环氧氯丙烷用量为0.3%,中和度为86%时,吸水率达53.18 g/g.同时研究了树脂的重复吸水率及保水性,发现该树脂的重复吸水效果较好、保水性能良好.通过红外谱图分析,AA与PE成功接枝.
以廢棄聚乙烯(PE)塑料與丙烯痠(AA)及其鹽為原料,採用微波加熱法接枝共聚閤成一種吸水樹脂.研究瞭引髮劑用量、交聯劑種類、AA中和度對樹脂吸水率的影響,髮現噹引髮劑用量為單體的4%、交聯劑環氧氯丙烷用量為0.3%,中和度為86%時,吸水率達53.18 g/g.同時研究瞭樹脂的重複吸水率及保水性,髮現該樹脂的重複吸水效果較好、保水性能良好.通過紅外譜圖分析,AA與PE成功接枝.
이폐기취을희(PE)소료여병희산(AA)급기염위원료,채용미파가열법접지공취합성일충흡수수지.연구료인발제용량、교련제충류、AA중화도대수지흡수솔적영향,발현당인발제용량위단체적4%、교련제배양록병완용량위0.3%,중화도위86%시,흡수솔체53.18 g/g.동시연구료수지적중복흡수솔급보수성,발현해수지적중복흡수효과교호、보수성능량호.통과홍외보도분석,AA여PE성공접지.
PE-AA Water-absorbent Resin was synthesized with waste plastic PE and acrylic acid(AA) by microwave ir- radiation. This paper studies on the dosage of initiator, the kind of crosslinker, the effects of AA neutralization degree on water absorption rate. The water absorption rate was .53.18 g/g, when the dosage of initiator of the mass monomers was 4% , and the crosslinker epoxy chloropropane( based on the mass of monomers) 0. 3%. Studies on the rate of repetition water absorption and water retention of resin found that the resin repetition absorbing effect and the water retention was good. By infrared spectrum analysis, AA and PE have been grafted.