CAJ | 학술논문

以改性纳米SiO2、γ-甲基丙烯酰氧基丙基三甲氧基硅烷（KH．570）、磷酸酯三丙烯酸酯（TEAP）及TDI-TMP加成物作紫外（uv）配方体系的功能成分，制备了含P、N及Si三重固化丙烯酸酯涂层。通过红外、紫外-可见、热重及阻燃性能测试仪等研究了不同阻燃体系下不同固化方式对环氧丙烯酸酯（EA）涂层阻燃及热稳定性能的影响。结果表明：EA体系双键转化率随纳米SiO2含量及固化重数的增加而提高；可见光透过率随KH-570、TDI-TMP的加入而改善；涂层阻燃及热稳定性随阻燃成分与其含量，及固化重数的增加而提高。
이개성납미SiO2、γ-갑기병희선양기병기삼갑양기규완（KH．570）、린산지삼병희산지（TEAP）급TDI-TMP가성물작자외（uv）배방체계적공능성분，제비료함P、N급Si삼중고화병희산지도층。통과홍외、자외-가견、열중급조연성능측시의등연구료불동조연체계하불동고화방식대배양병희산지（EA）도층조연급열은정성능적영향。결과표명：EA체계쌍건전화솔수납미SiO2함량급고화중수적증가이제고；가견광투과솔수KH-570、TDI-TMP적가입이개선；도층조연급열은정성수조연성분여기함량，급고화중수적증가이제고。
Triple-curing acrylic coatings containing P-N-Si were prepared, with modified nano-SiO2, 3,-methyl propylene acyloxy propyl trimethoxy silane(KH-570), phosphate three acrylate (TEAP)and TDI-TMP addition product as UV formula system's functional component. The effects of different flame retardant system and curing method on flame retardant and thermostability of epoxy acrylate (EA) coating weres studied by FT-IR, UV-Vis, TG, flame retardation measure instrument and so on. The result showed that C=C double bond conversion of EA system increased with nano-SiO2 content and curing layer number increasing, visible light transmittance was improved with KH-570 and TDI-TMP added, and that thermal stability and flame retardancy of acrylic coating were enhanced with flame retardant composition and its content and curing layer number increasing.