CAJ | 학술논문

以苯肼盐酸盐为原料,将其与甲基异丙基酮通过闭环反应,生成2,3,3-三甲基吲哚的衍生物,再经过与溴乙烷、六溴己酸反应成吲哚盐,然后和二甲脒反应得到吲哚乙烯基苯胺,最后合成了两种不同取代基团的水溶性的不对称三甲川吲哚菁染料,并通过核磁、质谱等测试手段对其结构进行表征.研究了该染料的紫外吸收光谱和荧光光谱.
이분정염산염위원료,장기여갑기이병기동통과폐배반응,생성2,3,3-삼갑기신타적연생물,재경과여추을완、륙추기산반응성신타염,연후화이갑미반응득도신타을희기분알,최후합성료량충불동취대기단적수용성적불대칭삼갑천신타정염료,병통과핵자、질보등측시수단대기결구진행표정.연구료해염료적자외흡수광보화형광광보.
The 2,3,3-trimethyl indole derivatives were synthesized by closed-loop reaction from phenylhydrazine derivatives and methyl isopropyl ketone.Then the 2,3,3-trimethyl indole derivatives were alkylated by ethyl bromide,6-bromhexine acid to afford indole salts,which then were reacted with N,N＇-diphenylformamidine to get indole ethylene aniline.At last,the unsymmetrical water soluble cyanine dyes with two different functional groups were synthesized.The structures of the dyes were characterized by 1HNMR,MS.The UV absorption and fluorescence spectra of the dyes were also studied.