宝石和宝石学杂志
寶石和寶石學雜誌
보석화보석학잡지
Journal of Gems & gemmology
2012年
1期
7-13
,共7页
陈琼%周征宇%姚春茂%袁媛%支颖雪
陳瓊%週徵宇%姚春茂%袁媛%支穎雪
진경%주정우%요춘무%원원%지영설
“坑头冻”%“青海白”%“丹东白”%“岩门晶”%地开石%斜绿泥石
“坑頭凍”%“青海白”%“丹東白”%“巖門晶”%地開石%斜綠泥石
“갱두동”%“청해백”%“단동백”%“암문정”%지개석%사록니석
'Kengtoudong'%'Qinghaibai'%'Dandongbai'%'Yanmenjing'%dickite%clinochlore
为研究缅甸翡翠中的哪些部位适合做烧红处理以及该部位能被烧红的原因,采用加热实验、偏光显微镜、红外光谱及差热分析方法对缅甸翡翠样品的原生部位、雾部位的加热前、后的特征进行了测试与分析。结果显示,翡翠中的蓝雾部位及黄雾部位适合做烧红处理,原生部位不适合烧红处理,蓝雾部位可以被烧成黄色及红色,黄雾部位可以被烧成红色。雾部位适合用来做烧红处理的原因在于,在低温的加热条件下,蓝雾部位中的大量的Fe2+发生价态变化,实现由绿泥石向针铁矿的转变所导致,该过程由表及里逐步进行。原生部位的主要矿物硬玉需被加热更高的温度,在破坏其晶格的情况下,才可以呈现出红色,且该红色不具有褐色调。
為研究緬甸翡翠中的哪些部位適閤做燒紅處理以及該部位能被燒紅的原因,採用加熱實驗、偏光顯微鏡、紅外光譜及差熱分析方法對緬甸翡翠樣品的原生部位、霧部位的加熱前、後的特徵進行瞭測試與分析。結果顯示,翡翠中的藍霧部位及黃霧部位適閤做燒紅處理,原生部位不適閤燒紅處理,藍霧部位可以被燒成黃色及紅色,黃霧部位可以被燒成紅色。霧部位適閤用來做燒紅處理的原因在于,在低溫的加熱條件下,藍霧部位中的大量的Fe2+髮生價態變化,實現由綠泥石嚮針鐵礦的轉變所導緻,該過程由錶及裏逐步進行。原生部位的主要礦物硬玉需被加熱更高的溫度,在破壞其晶格的情況下,纔可以呈現齣紅色,且該紅色不具有褐色調。
위연구면전비취중적나사부위괄합주소홍처리이급해부위능피소홍적원인,채용가열실험、편광현미경、홍외광보급차열분석방법대면전비취양품적원생부위、무부위적가열전、후적특정진행료측시여분석。결과현시,비취중적람무부위급황무부위괄합주소홍처리,원생부위불괄합소홍처리,람무부위가이피소성황색급홍색,황무부위가이피소성홍색。무부위괄합용래주소홍처리적원인재우,재저온적가열조건하,람무부위중적대량적Fe2+발생개태변화,실현유록니석향침철광적전변소도치,해과정유표급리축보진행。원생부위적주요광물경옥수피가열경고적온도,재파배기정격적정황하,재가이정현출홍색,차해홍색불구유갈색조。
Shoushan "Kengtoudong" is a typical stone of Shoushan puddle stone which is rare and expensive.By XRD,FTIR,ICP-MS,SEM and other instruments,mineral component,chemical composition,microstructure of "Qinghaibai""Dandongbai" and "Yanmenjing" are investigated systematically when they appear on the market recently as the imitation of Shoushan "Kengtoudong".The results show that "Kengtoudong" is mainly composed of dickite,observed with typical "Luobosiwen",and a higher percentage of Fe in chemical composition might result from its pyrite inclusions."Qinghaibai" is mainly composed of gypsum,which is of lower hardness."Dandongbai" is mainly composed of clinochlore,and dark green speckle impurities lead to dusky appearance."Yanmenjing" is mainly composed of dickite and higher V and Cr might be the reason that the stone show limegreen tones.SEM observation shows that Shoushan "Kengtoudong" samples have a high degree of crystallization with false hexagonal flake structure.The crystals plate of "Qinghaibai" is of large granularity,thickness and loose accumulation,thus it can be easily distinguished from others.The lamellar crystal of clinochlore of "Dandongbai" is thin and piled up closely,flex developed,thus it is smooth to the touch.The microscopical features of "Yanmenjing" are much like Shoushan "Kengtoudong",but its crystal degree is a little lower.The stones mentioned above are different in colour,luster,weighting and inclusions,due to their different mineral components and chemical compositions.