广州化工
廣州化工
엄주화공
GUANGZHOU CHEMICAL INDUSTRY AND TECHNOLOGY
2012年
14期
77-79,109
,共4页
林聪妹%刘世俊%张娟%潘丽萍%张建虎
林聰妹%劉世俊%張娟%潘麗萍%張建虎
림총매%류세준%장연%반려평%장건호
TATB基PBX%增强技术%力学性能%动态力学分析
TATB基PBX%增彊技術%力學性能%動態力學分析
TATB기PBX%증강기술%역학성능%동태역학분석
TATB -based PBX%enhancement technology%mechanical properties%dynamic mechanical analysis
采用熔融共混法制备了氟聚合物/增强剂复合粘结剂体系,考察了增强剂含量对复合粘结剂体系性能的影响。动态力学分析(DMA)结果显示,增强剂的玻璃化转变温度大大高于氟聚合物,复合粘结剂体系的储能模量随增强剂含量的增加而增加。随着增强剂含量增加,复合粘结剂体系的拉伸强度明显增加。采用水悬浮法制备了TATB基高聚物粘结炸药(PBX),探讨了粘结剂增强对其力学性能的影响。实验结果表明,随着增强剂含量增加,TATB基PBX的力学性能显著提高。当复合粘结剂体系中增强剂含量为20%时,PBX的力学性能最佳:20℃和60℃下压缩强度为32.15MPa和20.00MPa,60℃下劈裂强度为2.84MPa。
採用鎔融共混法製備瞭氟聚閤物/增彊劑複閤粘結劑體繫,攷察瞭增彊劑含量對複閤粘結劑體繫性能的影響。動態力學分析(DMA)結果顯示,增彊劑的玻璃化轉變溫度大大高于氟聚閤物,複閤粘結劑體繫的儲能模量隨增彊劑含量的增加而增加。隨著增彊劑含量增加,複閤粘結劑體繫的拉伸彊度明顯增加。採用水懸浮法製備瞭TATB基高聚物粘結炸藥(PBX),探討瞭粘結劑增彊對其力學性能的影響。實驗結果錶明,隨著增彊劑含量增加,TATB基PBX的力學性能顯著提高。噹複閤粘結劑體繫中增彊劑含量為20%時,PBX的力學性能最佳:20℃和60℃下壓縮彊度為32.15MPa和20.00MPa,60℃下劈裂彊度為2.84MPa。
채용용융공혼법제비료불취합물/증강제복합점결제체계,고찰료증강제함량대복합점결제체계성능적영향。동태역학분석(DMA)결과현시,증강제적파리화전변온도대대고우불취합물,복합점결제체계적저능모량수증강제함량적증가이증가。수착증강제함량증가,복합점결제체계적랍신강도명현증가。채용수현부법제비료TATB기고취물점결작약(PBX),탐토료점결제증강대기역학성능적영향。실험결과표명,수착증강제함량증가,TATB기PBX적역학성능현저제고。당복합점결제체계중증강제함량위20%시,PBX적역학성능최가:20℃화60℃하압축강도위32.15MPa화20.00MPa,60℃하벽렬강도위2.84MPa。
Composite binders (CB) based on fluoropolymer and reinforcing agent (RA) were obtained via a melt blending process to explore the influences of RA on the properties of CB. The results of dynamic mechanical analysis (DMA) suggested that the glass transition temperature(Tg) of RA was much higher than that of fluoropolymer. As RA content increased, the storage modulus(E' ) of CB increased. The tensile strength of CB increased with increasing RA content. TATB- based polymer bonded explosive (PBX) was prepared with water suspension methods. The effects of binder enhancement technology on the mechanical properties of PBX were investigated. The experimental results indicated that the mechanical properties of TATB - based explosives significantly increased with increasing of RA content. When RA concentration in CB was 20%, TATB - based explosives showed the best performance with compresssive strength of 32. 15 MPa and 20.00 MPa at 20℃ and 60℃, split strength of 2.84 MPa at 60℃. respectively