CAJ | 학술논문

利用5,5’-亚甲基-双水杨醛与苯胺缩合反应合成了新型Schiff碱,通过核磁共振技术及红外光谱法进行了表征,并获得了其晶体结构。该晶体属于单斜晶系,空间群为：C2/c,相关晶胞参数为：a=4.3954（12）nm,b=1.0150（2）nm,c=0.9576（2）nm,β=90.822（10）°,V=4.2717（17）nm3。该化合物存在分子内氢键,每相邻的分子之间通过分子间的氢键以及C-H…π作用将化合物连接成为Z字型结构,且该化合物有一定的抑菌活性。
이용5,5’-아갑기-쌍수양철여분알축합반응합성료신형Schiff감,통과핵자공진기술급홍외광보법진행료표정,병획득료기정체결구。해정체속우단사정계,공간군위：C2/c,상관정포삼수위：a=4.3954（12）nm,b=1.0150（2）nm,c=0.9576（2）nm,β=90.822（10）°,V=4.2717（17）nm3。해화합물존재분자내경건,매상린적분자지간통과분자간적경건이급C-H…π작용장화합물련접성위Z자형결구,차해화합물유일정적억균활성。
A novel Schiff base compounds containing bis-salicylaldehyde（2） was synthesized and structurally characterized by 1H NMR techniques,IR and single crystal X-ray diffraction structural determination.Crystal data were monoclinic,space group： C2/c,a=4.3954（12） nm,b=1.0150（2） nm,c=0.9576（2） nm,β=90.822（10）°,and V=4.2717（17） nm3.In the crystal structure of compound 2,there were intramolecular hydrogen bonds,and the Z shape chain structure formed by intermolecular hydrogen bonds and C-H…π interaction.The bacteriostatic activity results indicated that the compound possessed some bacteriostatic effect.