国外塑料
國外塑料
국외소료
WORLD PLASTICS
2012年
10期
65-69
,共5页
张会平%何慧%赵小科%贾德民
張會平%何慧%趙小科%賈德民
장회평%하혜%조소과%가덕민
木塑复合材料%阻燃性能%聚磷酸铵%硼酸锌%硅藻土
木塑複閤材料%阻燃性能%聚燐痠銨%硼痠鋅%硅藻土
목소복합재료%조연성능%취린산안%붕산자%규조토
Wood-plastic Composites%Flame Retardancy%Ammonium Polyphosphate%Zinc Borate%Kieselguhr
采用无卤阻燃剂聚磷酸铵(APP)以及阻燃协效剂硼酸锌(zB)、硅藻土,制备具有良好阻燃性能的木塑复合材料。结果表明:APP在改善木塑复合材料阻燃性能的同时,可提高材料的热稳定性,当其用量为20份时,复合材料垂直燃烧达到UL94V-0级,此时,体系的力学性能变化不大;ZB、硅藻土对木塑复合材料的协效阻燃规律不同于对塑料的阻燃规律,添加2份硅藻土的阻燃体系形成的炭层最致密,可有效地隔热隔氧。
採用無滷阻燃劑聚燐痠銨(APP)以及阻燃協效劑硼痠鋅(zB)、硅藻土,製備具有良好阻燃性能的木塑複閤材料。結果錶明:APP在改善木塑複閤材料阻燃性能的同時,可提高材料的熱穩定性,噹其用量為20份時,複閤材料垂直燃燒達到UL94V-0級,此時,體繫的力學性能變化不大;ZB、硅藻土對木塑複閤材料的協效阻燃規律不同于對塑料的阻燃規律,添加2份硅藻土的阻燃體繫形成的炭層最緻密,可有效地隔熱隔氧。
채용무서조연제취린산안(APP)이급조연협효제붕산자(zB)、규조토,제비구유량호조연성능적목소복합재료。결과표명:APP재개선목소복합재료조연성능적동시,가제고재료적열은정성,당기용량위20빈시,복합재료수직연소체도UL94V-0급,차시,체계적역학성능변화불대;ZB、규조토대목소복합재료적협효조연규률불동우대소료적조연규률,첨가2빈규조토적조연체계형성적탄층최치밀,가유효지격열격양。
Fire retardant ammonium polyphosphate (APP) and FR synergist zinc borate(ZB) and kieselguhr were applied to prepare flame retarding wood-plastic composites. The burning behavior was studied through horizontal-vertical burning and limiting oxygen index (LOI). Thermogravimetric analysis (TGA) was employed to measure the thermal stability and the mechanical properties of the composites were tested statically. The results showed that APP enhanced the thermal stability of the composites significantly. When the APP content was 20 phr, the UL94 was V-0 rating, while the mechanical properties didn't change obviously. The synergistic effect of ZB and kieselguhr was not sharp, which indicated that the flame retardancy laws of them in wood-plastic composites were different from that in plastic. The SEM analysis demonstrated that the carbon layer of specimen of 2 phr kieselguhr was continuously denser and insulated heat and oxgen effectively.