上海化工
上海化工
상해화공
SHANGHAI CHEMICAL INDUSTRY
2012年
11期
5-8
,共4页
陈芳%周浪%邓真丽%陆江林
陳芳%週浪%鄧真麗%陸江林
진방%주랑%산진려%륙강림
溶胶-凝胶法%稀土Y^3+掺杂%TiO2%光催化%刚果红
溶膠-凝膠法%稀土Y^3+摻雜%TiO2%光催化%剛果紅
용효-응효법%희토Y^3+참잡%TiO2%광최화%강과홍
Sol-gel%Rare earth Y^3+ doping%Titanium dioxide%Photocatalytic%Congo red
用溶胶-凝胶法制备了稀土Y^3+掺杂TiO2,对其进行了XRD分析,以刚果红溶液为目标降解物研究了稀土Y^3+掺杂TiO2的光催化性能。结果表明:同等实验条件下Y^3+掺杂TiO2比纯TiO2的降解效果好。当稀土Y^3+的掺杂量n(Y^3+):n(TiO2)=0.5%(摩尔比)、焙烧温度600℃、刚果红溶液初始浓度20mg/L、pH=3、催化剂用量为1.5g/L时,其光催化性能最佳。反应1h的降解率可达98.55%。
用溶膠-凝膠法製備瞭稀土Y^3+摻雜TiO2,對其進行瞭XRD分析,以剛果紅溶液為目標降解物研究瞭稀土Y^3+摻雜TiO2的光催化性能。結果錶明:同等實驗條件下Y^3+摻雜TiO2比純TiO2的降解效果好。噹稀土Y^3+的摻雜量n(Y^3+):n(TiO2)=0.5%(摩爾比)、焙燒溫度600℃、剛果紅溶液初始濃度20mg/L、pH=3、催化劑用量為1.5g/L時,其光催化性能最佳。反應1h的降解率可達98.55%。
용용효-응효법제비료희토Y^3+참잡TiO2,대기진행료XRD분석,이강과홍용액위목표강해물연구료희토Y^3+참잡TiO2적광최화성능。결과표명:동등실험조건하Y^3+참잡TiO2비순TiO2적강해효과호。당희토Y^3+적참잡량n(Y^3+):n(TiO2)=0.5%(마이비)、배소온도600℃、강과홍용액초시농도20mg/L、pH=3、최화제용량위1.5g/L시,기광최화성능최가。반응1h적강해솔가체98.55%。
The titanium dioxide (TiO2) doped with Y^3+ was prepared by sol-gel and characterized by means of XRD. Photocatalysis performance of TiO2 doped with Y^3+ was studied targeting congo red solution. The results showed that under the same conditions of preparation, the degradation effect of TiO2 doped with Y^3+ was better than pure TiO2. When the molar ratio of Y^3+ and TiO2 was 0.5, the calcination temperature was 600 ~C, the initial concentration of congo red solution was 20 rag/L, the pH value was 3,and the dosage of TiO,. was 1.5 g/L, the photocatalytic properties of TiO2 was best. And the degradation rate reached 98.55% after degradation for 1 hour.