CAJ | 학술논문

以1,2-二胺氧乙烷和4-羟基水杨醛为原料,在无水乙醇溶剂中合成了Salen双肟类配体5,5′-二羟基-2,2′-[乙二氧双（氮次甲基）]二酚（H4L）。以丙酮为溶剂,将H4L与一水合乙酸铜在室温下反应,制备了一种新的Salen双肟类乙酸铜配合物。通过元素分析、核磁共振氢谱、红外光谱、紫外光谱及差热-热重等表征方法得知配合物的可能结构式为[Cu（C16H14N2O6）].2H2O。
이1,2-이알양을완화4-간기수양철위원료,재무수을순용제중합성료Salen쌍우류배체5,5′-이간기-2,2′-[을이양쌍（담차갑기）]이분（H4L）。이병동위용제,장H4L여일수합을산동재실온하반응,제비료일충신적Salen쌍우류을산동배합물。통과원소분석、핵자공진경보、홍외광보、자외광보급차열-열중등표정방법득지배합물적가능결구식위[Cu（C16H14N2O6）].2H2O。
A Salen-- type bisoxime ligand 5,5＂-- Dihydroxy-- 2, 2＂[-ethylenedioxybis （nitrilomethylidyne） diphenol （H4L） was synthesized in anhydrous ethanol solvent by the means of 1, 2--bis（aminooxy） ethane with 2, 4--dihydroxybenzaldehyde. A novel Salen--type bisoxime cupric acetate complex was also synthesized in acetone by the reaction of H4L and copper（II） acetate monohydrate at room temper- ature. The compounds were characterized by elemental analysis, 1H NMR, IR, UV and TG--DTA. The results indicated that the structural formula of the complex was suggested asFCu （C16 H14 N206）~ 2H20.