广东化工
廣東化工
엄동화공
GUANGDONG CHEMICAL INDUSTRY
2012年
7期
42-44
,共3页
樊红超%南慧芳%陈宜俍%汪毅%张忠东
樊紅超%南慧芳%陳宜俍%汪毅%張忠東
번홍초%남혜방%진의량%왕의%장충동
高岭土微球:陈化:晶化%时间%温度
高嶺土微毬:陳化:晶化%時間%溫度
고령토미구:진화:정화%시간%온도
kaolin microsphere%aging%crystallized%time%temperature
以高岭土微球为原料,以KOH为碱源合成L沸石。主要考察了陈化温度、陈化时间、晶化温度、晶化时间以及陈化后晶化时间对合成L沸石的影响。实验结果表明:陈化温度对合成沸石分子筛的相对结晶度影响较小;合成L沸石的相对结晶度随着晶化温度的升高而增大,但是晶化温度高于130℃以后,沸石分子筛的相对结晶度反而下降:陈化时间的长短对合成沸石分子筛影响较小,但是合成沸石分子筛的相对结晶度随着晶化时间增长而升高。
以高嶺土微毬為原料,以KOH為堿源閤成L沸石。主要攷察瞭陳化溫度、陳化時間、晶化溫度、晶化時間以及陳化後晶化時間對閤成L沸石的影響。實驗結果錶明:陳化溫度對閤成沸石分子篩的相對結晶度影響較小;閤成L沸石的相對結晶度隨著晶化溫度的升高而增大,但是晶化溫度高于130℃以後,沸石分子篩的相對結晶度反而下降:陳化時間的長短對閤成沸石分子篩影響較小,但是閤成沸石分子篩的相對結晶度隨著晶化時間增長而升高。
이고령토미구위원료,이KOH위감원합성L비석。주요고찰료진화온도、진화시간、정화온도、정화시간이급진화후정화시간대합성L비석적영향。실험결과표명:진화온도대합성비석분자사적상대결정도영향교소;합성L비석적상대결정도수착정화온도적승고이증대,단시정화온도고우130℃이후,비석분자사적상대결정도반이하강:진화시간적장단대합성비석분자사영향교소,단시합성비석분자사적상대결정도수착정화시간증장이승고。
In the study zeolite L was synthesized with kaolin microspheres as raw materials and potassium hydroxide as alkali sources. The effects of aged temperature and time, crystallization temperature and time and the different crystallization under aging on the zeolite L were investigated .The changing of aged temperatures had a slight effects on the relative crystalline of synthesis of molecular sieves; It was conclused that relative crystalline of synthesis of molecular sieves increase with the increasing of crystallization temperature, but went down when the crystallization temperature above 130 ℃. The aging times had no effects on the synthesis of molecular sieves in the study. The relative crystalline of synthesis of molecular sieves were going large with the increasing of crystallization time.