广州化工
廣州化工
엄주화공
GUANGZHOU CHEMICAL INDUSTRY AND TECHNOLOGY
2012年
8期
122-123,125
,共3页
AlCl3/NaHSO4%乙酸正丁酯%合成
AlCl3/NaHSO4%乙痠正丁酯%閤成
AlCl3/NaHSO4%을산정정지%합성
AlCl3/NaHSO4%n - butyl acetate%synthesis
探讨了以AlCl3/NaHSO4为复合催化剂,冰醋酸、正丁醇为原料合成乙酸正丁酯。确定了反应的优化条件：当冰醋酸用量为0.1 mol时,反应物料的投料物质的量比n（冰醋酸）∶n（正丁酯）=1∶1.7,催化剂配料物质的量比为n（AlCl3）∶n（NaHSO4）=1∶1.5,催化剂用量2 g,15 mL环己烷作带水剂,回流温度下反应时间为120 min,其酯化率达97%。
探討瞭以AlCl3/NaHSO4為複閤催化劑,冰醋痠、正丁醇為原料閤成乙痠正丁酯。確定瞭反應的優化條件：噹冰醋痠用量為0.1 mol時,反應物料的投料物質的量比n（冰醋痠）∶n（正丁酯）=1∶1.7,催化劑配料物質的量比為n（AlCl3）∶n（NaHSO4）=1∶1.5,催化劑用量2 g,15 mL環己烷作帶水劑,迴流溫度下反應時間為120 min,其酯化率達97%。
탐토료이AlCl3/NaHSO4위복합최화제,빙작산、정정순위원료합성을산정정지。학정료반응적우화조건：당빙작산용량위0.1 mol시,반응물료적투료물질적량비n（빙작산）∶n（정정지）=1∶1.7,최화제배료물질적량비위n（AlCl3）∶n（NaHSO4）=1∶1.5,최화제용량2 g,15 mL배기완작대수제,회류온도하반응시간위120 min,기지화솔체97%。
Based on the composition of n - butyl acetate by using AlCl3/NaHSO4 as catalyst, acetate and n - butyl as raw materials, the optimum conditions were determined. The results showed n （acetate） ： n （ rr - butyl ） = 1 ： 1.7, the catalyst 2 g, water- carrying agent cyclohexane 15 mL, the reaction time 120 min, the esterification rate 97%, and the amount of acetic acid was 0.1 tool.
