广州化工
廣州化工
엄주화공
GUANGZHOU CHEMICAL INDUSTRY AND TECHNOLOGY
2012年
8期
49-50,67
,共3页
离子液体%均相催化%加氢%氢甲酰化
離子液體%均相催化%加氫%氫甲酰化
리자액체%균상최화%가경%경갑선화
ionic liquid%homogeneous catalysis%hydrogenation%hydroformylation
综述了近年来离子液体/有机两相均相催化的研究进展,重点介绍了基于氟硼酸根(BF4-)或氟磷酸根(PF6-)的咪唑类离子液体在均相催化加氢、氢甲酰化、齐聚、Heck反应中的应用,并对离子液体/有机两相催化工业应用的前景进行了探讨。
綜述瞭近年來離子液體/有機兩相均相催化的研究進展,重點介紹瞭基于氟硼痠根(BF4-)或氟燐痠根(PF6-)的咪唑類離子液體在均相催化加氫、氫甲酰化、齊聚、Heck反應中的應用,併對離子液體/有機兩相催化工業應用的前景進行瞭探討。
종술료근년래리자액체/유궤량상균상최화적연구진전,중점개소료기우불붕산근(BF4-)혹불린산근(PF6-)적미서류리자액체재균상최화가경、경갑선화、제취、Heck반응중적응용,병대리자액체/유궤량상최화공업응용적전경진행료탐토。
The development of ionic liquid - organic two - phasic catalysis was summerized, the applications of imid- azole class ionic liquid based were introduced with emphasis based on the fluoboric acid anion ( BF4- ) or the hexafluoro- phosphoric acid anion (PF6- ) in homogeneous catalysis hydrogenation, hydroformylation, oligomerization, Heek reaction, and the future applications of ionic liquid - organic biphasic catalysis in chemical industry were commented.