CAJ | 학술논문

采用平推流管式反应器，通过对四个相同规格反应器的串、并联组合，形成两种串并联反应器系统，并用于制备苯乙烯-丙烯腈塑料(SAN)。分别讨论了四釜串联和两组两釜串联的并联组合形式下，温度、链转移剂浓度等因素对物料固含量、冲击强度、分子量及其分布的影响。结果表明，四个平推流反应器的串联组合，可形成四釜串联结构的聚合系统，通过每个聚合反应釜的聚合条件控制，可以实现SAN的聚合过程，SAN样品中丙烯腈含量在24%～28%之间。通过两个平推流反应器串联，并部分物流循环的方式，可以实现两组两串联循环反应器的并联组合，在保持四反应器的基础上，使反应体系生产能力倍增。
채용평추류관식반응기，통과대사개상동규격반응기적천、병련조합，형성량충천병련반응기계통，병용우제비분을희-병희정소료(SAN)。분별토론료사부천련화량조량부천련적병련조합형식하，온도、련전이제농도등인소대물료고함량、충격강도、분자량급기분포적영향。결과표명，사개평추류반응기적천련조합，가형성사부천련결구적취합계통，통과매개취합반응부적취합조건공제，가이실현SAN적취합과정，SAN양품중병희정함량재24%～28%지간。통과량개평추류반응기천련，병부분물류순배적방식，가이실현량조량천련순배반응기적병련조합，재보지사반응기적기출상，사반응체계생산능력배증。
Using plug flow tubular reactors,through series and parallel combination of four same specification reactors,two series and parallel reactor systems were formed,and were used to prepare styrene acrylonitrile plastic (SAN). While four reactors in series and two parallel combination of two reactor in series,the influence of factors such as temperature,chain transfer agent concentration on solid content,impact strength,molecular weight and its distribution was discussed separately. The results show that the series combination of four plug flow reactor can form polymerization system of four reactors in series,through the control of polymerization conditions of each reactors,the polymerization process of SAN can be realized,acrylonitrile content in SAN samples is adjusted between 24%~28%. Through the two plug flow reactor in series and part of the logistics cyclic manner,two parallel combination group of two reactors in series is realised,which doubled production capacity of the reaction system while keeping four reactors.