中国环境科学
中國環境科學
중국배경과학
CHINA ENVIRONMENTAL SCIENCE
2014年
1期
201-206
,共6页
许治国%朱能武%杨崇%吴平霄
許治國%硃能武%楊崇%吳平霄
허치국%주능무%양숭%오평소
废旧线路板%生物浸出%反应器%有价金属%氧化亚铁硫杆菌
廢舊線路闆%生物浸齣%反應器%有價金屬%氧化亞鐵硫桿菌
폐구선로판%생물침출%반응기%유개금속%양화아철류간균
waste printed circuit boards%bioleaching%reactor%valuable metals%Thiobacillus ferrooxidans
为探讨可供实际生物浸出应用的反应器规模废旧线路板中有价金属浸出特性和工艺条件,通过设计序批式生物浸出反应器,采用分离到的氧化亚铁硫杆菌 Z1作为菌种资源,在考察废旧线路板中有价金属的浸出特性的基础上,确定了反应器运行的最佳工艺条件.结果表明,反应器运行的最佳工艺条件为曝气量1L/min、停留时间30h、搅拌速率300r/min以及粉末投加量12g/L.在此条件下,经过101h可以浸出90.24%的铜.同时,经197h的浸出,可以溶出93.06%的镁、92.00%的锌、85.59%的铝和64.51%的镍.因此,生物浸出反应器能有效回收废旧线路板中的有价金属,为该技术的实际应用提供了实验证据.
為探討可供實際生物浸齣應用的反應器規模廢舊線路闆中有價金屬浸齣特性和工藝條件,通過設計序批式生物浸齣反應器,採用分離到的氧化亞鐵硫桿菌 Z1作為菌種資源,在攷察廢舊線路闆中有價金屬的浸齣特性的基礎上,確定瞭反應器運行的最佳工藝條件.結果錶明,反應器運行的最佳工藝條件為曝氣量1L/min、停留時間30h、攪拌速率300r/min以及粉末投加量12g/L.在此條件下,經過101h可以浸齣90.24%的銅.同時,經197h的浸齣,可以溶齣93.06%的鎂、92.00%的鋅、85.59%的鋁和64.51%的鎳.因此,生物浸齣反應器能有效迴收廢舊線路闆中的有價金屬,為該技術的實際應用提供瞭實驗證據.
위탐토가공실제생물침출응용적반응기규모폐구선로판중유개금속침출특성화공예조건,통과설계서비식생물침출반응기,채용분리도적양화아철류간균 Z1작위균충자원,재고찰폐구선로판중유개금속적침출특성적기출상,학정료반응기운행적최가공예조건.결과표명,반응기운행적최가공예조건위폭기량1L/min、정류시간30h、교반속솔300r/min이급분말투가량12g/L.재차조건하,경과101h가이침출90.24%적동.동시,경197h적침출,가이용출93.06%적미、92.00%적자、85.59%적려화64.51%적얼.인차,생물침출반응기능유효회수폐구선로판중적유개금속,위해기술적실제응용제공료실험증거.
To explore the bioleaching characteristics and process conditions of valuable metals in bioreactor which from waste printed circuit boards so as to promote the practical application of bioleaching technology, the designed batch mode bioleaching reactor and was used and strain Thiobacillus ferrooxidans Z1 was isolated, the optimum operation conditions of bioreactor was determined on the basis of investigation of bioleaching characteristics of valuable metals from waste printed circuit boards. The results showed that the optimum operation conditions of the reactor was:aeration rate 1L/min, retention time 30h, stirring speed 300r/min and powder dosages 12g/L. Under the conditions, 90.24% copper leaching efficiency was achieved in 101h. Meanwhile, 93.06%of magnesium, 85.59%of zinc, 85.59%of aluminium and 64.51%of nickel was bioleached in 197h, respectively. Therefore, the bioleaching reactor can effectively recover valuable metals in the waste printed circuit boards, which provided experimental evidence for the practical application of the technology.