中国环境科学
中國環境科學
중국배경과학
CHINA ENVIRONMENTAL SCIENCE
2014年
1期
150-155
,共6页
邬艳%杨艳玲%李星%周志伟%王伟强%苏兆阳
鄔豔%楊豔玲%李星%週誌偉%王偉彊%囌兆暘
오염%양염령%리성%주지위%왕위강%소조양
混凝机理%混凝效能%絮凝指数%分形维数%比表面积
混凝機理%混凝效能%絮凝指數%分形維數%比錶麵積
혼응궤리%혼응효능%서응지수%분형유수%비표면적
coagulation mechanism%coagulation efficiency%flocculation index%fractal dimension%specific surface
以模拟低浊微污染水为原水,硫酸铝[Al2(SO4)3]为混凝剂,考察了3种常见混凝机理(电性中和、吸附架桥和网捕卷扫)为主导条件下絮体的成长过程、二维边界分形维数(Dpf)和比表面积及其与混凝效果的相关性.结果表明:吸附架桥为主导机理下絮体最大增长速率 S (0.951)最快,达到稳定后絮凝指数FI最大(3.7%),二维边界分形维数Dpf最大(1.587),絮体呈块状且絮体间出现孔状间隙,比表面积介于网捕卷扫和电性中和之间[网捕卷扫(83.646m2/g)>吸附架桥(98.808m2/g)>电性中和(116.046m2/g)];FI值、S及Dpf变化与浊度去除率相关性较好,其相关系数分别达0.979、0.982和0.963,同时比表面积大的絮体吸附容量大,有机物的去除率高.
以模擬低濁微汙染水為原水,硫痠鋁[Al2(SO4)3]為混凝劑,攷察瞭3種常見混凝機理(電性中和、吸附架橋和網捕捲掃)為主導條件下絮體的成長過程、二維邊界分形維數(Dpf)和比錶麵積及其與混凝效果的相關性.結果錶明:吸附架橋為主導機理下絮體最大增長速率 S (0.951)最快,達到穩定後絮凝指數FI最大(3.7%),二維邊界分形維數Dpf最大(1.587),絮體呈塊狀且絮體間齣現孔狀間隙,比錶麵積介于網捕捲掃和電性中和之間[網捕捲掃(83.646m2/g)>吸附架橋(98.808m2/g)>電性中和(116.046m2/g)];FI值、S及Dpf變化與濁度去除率相關性較好,其相關繫數分彆達0.979、0.982和0.963,同時比錶麵積大的絮體吸附容量大,有機物的去除率高.
이모의저탁미오염수위원수,류산려[Al2(SO4)3]위혼응제,고찰료3충상견혼응궤리(전성중화、흡부가교화망포권소)위주도조건하서체적성장과정、이유변계분형유수(Dpf)화비표면적급기여혼응효과적상관성.결과표명:흡부가교위주도궤리하서체최대증장속솔 S (0.951)최쾌,체도은정후서응지수FI최대(3.7%),이유변계분형유수Dpf최대(1.587),서체정괴상차서체간출현공상간극,비표면적개우망포권소화전성중화지간[망포권소(83.646m2/g)>흡부가교(98.808m2/g)>전성중화(116.046m2/g)];FI치、S급Dpf변화여탁도거제솔상관성교호,기상관계수분별체0.979、0.982화0.963,동시비표면적대적서체흡부용량대,유궤물적거제솔고.
Simulated low turbidity and micro-polluted water was used as raw water and aluminium sulfate was used as coagulant,the flocs growth process, two-dimensional perimeter fractal dimension (Dpf), specific surface and the relationship between flocs characteristics and coagulation efficiency under three common coagulation mechanisms (charge neutralization, bridging and sweep flocculation) were investigated. The results indicated that the highest growth rate S (0.951), stable flocculation index (FI) value (3.7%) and two-dimensional perimeter fractal dimension (1.588) of flocs were formed under bridging dominated the coagulation mechanism. Additionally, the flocs stick together in clumps with porous space in such condition and its specific surface was between that formed by sweep flocculation and charge neutralization as the following hierarchy:sweep flocculation (83.646m2/g)>bridging (98.808m2/g)>charge neutralization (116.046m2/g). The FI value, S and Dpf had a significant linear correlation with the turbidity removal efficiency, the correlation coefficient reaching up to 0.979、0.982 and 0.963, respectively. The flocs with higher specific surface and bigger adsorption capacity may be contributed to a higher organic matter removal.