中国环境科学
中國環境科學
중국배경과학
CHINA ENVIRONMENTAL SCIENCE
2014年
1期
72-77
,共6页
化学磷沉淀%响应面分析法%变量分析
化學燐沉澱%響應麵分析法%變量分析
화학린침정%향응면분석법%변량분석
chemical phosphate precipitation%response surface methodology%variance analysis
在用铁盐对厌氧段富磷上清液进行化学磷沉淀以实现磷的回收和达标排放的 SBR 系统中,为了减少铁盐化学除磷残余物可能对生物处理系统的影响,采用Box-Benhnken中心组合试验原理和响应面分析法,选择Fe:P、混凝搅拌强度、絮凝搅拌强度、搅拌时间等为自变量,残余铁离子为响应值,研究自变量之间的交互作用,以期优化化学除磷条件.通过Design-Expert 8.0软件得到1个二次响应曲面模型.得出最佳除磷条件:Fe:P比为1.40:1,搅拌强度为275r/min,快速搅拌时间为30s,絮凝搅拌强度为60r/min,絮凝时间为18min,沉淀时间为20min.在此条件下,化学混凝后残余铁离子浓度为0.37mg/L,化学除磷率大于97.66%.
在用鐵鹽對厭氧段富燐上清液進行化學燐沉澱以實現燐的迴收和達標排放的 SBR 繫統中,為瞭減少鐵鹽化學除燐殘餘物可能對生物處理繫統的影響,採用Box-Benhnken中心組閤試驗原理和響應麵分析法,選擇Fe:P、混凝攪拌彊度、絮凝攪拌彊度、攪拌時間等為自變量,殘餘鐵離子為響應值,研究自變量之間的交互作用,以期優化化學除燐條件.通過Design-Expert 8.0軟件得到1箇二次響應麯麵模型.得齣最佳除燐條件:Fe:P比為1.40:1,攪拌彊度為275r/min,快速攪拌時間為30s,絮凝攪拌彊度為60r/min,絮凝時間為18min,沉澱時間為20min.在此條件下,化學混凝後殘餘鐵離子濃度為0.37mg/L,化學除燐率大于97.66%.
재용철염대염양단부린상청액진행화학린침정이실현린적회수화체표배방적 SBR 계통중,위료감소철염화학제린잔여물가능대생물처리계통적영향,채용Box-Benhnken중심조합시험원리화향응면분석법,선택Fe:P、혼응교반강도、서응교반강도、교반시간등위자변량,잔여철리자위향응치,연구자변량지간적교호작용,이기우화화학제린조건.통과Design-Expert 8.0연건득도1개이차향응곡면모형.득출최가제린조건:Fe:P비위1.40:1,교반강도위275r/min,쾌속교반시간위30s,서응교반강도위60r/min,서응시간위18min,침정시간위20min.재차조건하,화학혼응후잔여철리자농도위0.37mg/L,화학제린솔대우97.66%.
Ferric salt was used as precipitator for phosphorus removal from supernatant of a SBR at anaerobic stage to recovery phosphorus source. To reduce adverse effect of chemical residue on the microorganism and reclaim phosphorus resources as much as possible, Box-Benhnken center combination experimental principle and response surface methodology were adopted, rations of dosage of ferric salt to that of phosphate, agitation speed, flocculation reaction time were chosen as independent variable and residual ferric ion concentration for response value to explore the interaction among those parameters in this study. With the aid of Design-Expert 8.0 software, a quadratic curved surface model was obtained. The result showed that the optimum conditions to be a dose of 1.40:1molar ratio of ferric ion to phosphate, stirring intensity for 275r/min with 30s in coagulation and 60r/min with 18min in flocculation, and precipitation time of 20min. The residual iron ion concentration could be kept at 0.37mg/L, and the efficiency of phosphorus removal could be achieved more than 97.66%.