CAJ | 학술논문

通过种子乳液聚合法制备得到亲水核与核壳结构微球，采用酸碱溶胀法处理核壳微球，制备了微米级中空微球。扫描电子显微镜、透射电子显微镜等测试分析表明，单分散性的亲水核平均直径约465nm；单分散的核壳微球表面略显粗糙，平均直径约560nm，疏水壳层厚度约100nm；微米级中空微球的直径约1．20μm，中空度为21．6％，其单分散性与球形度良好。在亲水核聚合过程中，当m（MMA）／m（MAA）=1．77：1时，乳液反应体系稳定，得到亲水核微球的单分散性最好。
통과충자유액취합법제비득도친수핵여핵각결구미구，채용산감용창법처리핵각미구，제비료미미급중공미구。소묘전자현미경、투사전자현미경등측시분석표명，단분산성적친수핵평균직경약465nm；단분산적핵각미구표면략현조조，평균직경약560nm，소수각층후도약100nm；미미급중공미구적직경약1．20μm，중공도위21．6％，기단분산성여구형도량호。재친수핵취합과정중，당m（MMA）／m（MAA）=1．77：1시，유액반응체계은정，득도친수핵미구적단분산성최호。
Hollow polymer microspheres in micrometer scale based on latex polymerizing and acid alkai swelling were successfully prepared. As clearly revealed by the Scanning electron microscopy（SEM） and transmission electron microscope（TEM） indicates that the diameter of uniform hydrophilic latex cores is a- bout 465 nm. And the surfaces of core/shell particles with mean diameter 560 nm and thickness of hydro- phobic shell 100 nm are a little rough. The size of monodisperse hollow polymer microspheres is about 1.20μm. Their hollowness is 21.6%. When m （ MMA）/rn （MAA） equals to 1.77 ： 1, the latex sys- tem is stable and the synthesized hydrophilie latex cores show a significant monodisperse.