CAJ | 학술논문

溶剂热法合成了一个新的Mn配合物，[Mn（TBDZ）2]NO3·Cl·H2O（TBDZ=噻菌灵）．此配合物属于单斜晶系，P2（1）／c空间群，a=16．003（7）A，b=11．158（5）A，c=13．905（6）A，a=90．00°，β=113．196（5）°，γ=90．00°，V=2282．3（16）A^3，Z=4．每个锰离子分别与来自两个噻菌灵分子上的两个氮原子形成双螯合结构，同时还与另一个氯离子，一个配位水的氧原子配位，形成了一个变形的八面体结构．未配位的硝酸根离子与配位水，噻菌灵上的另一个亚胺基上的氢原子形成氢键，参与了配合物的空间连接．
용제열법합성료일개신적Mn배합물，[Mn（TBDZ）2]NO3·Cl·H2O（TBDZ=새균령）．차배합물속우단사정계，P2（1）／c공간군，a=16．003（7）A，b=11．158（5）A，c=13．905（6）A，a=90．00°，β=113．196（5）°，γ=90．00°，V=2282．3（16）A^3，Z=4．매개맹리자분별여래자량개새균령분자상적량개담원자형성쌍오합결구，동시환여령일개록리자，일개배위수적양원자배위，형성료일개변형적팔면체결구．미배위적초산근리자여배위수，새균령상적령일개아알기상적경원자형성경건，삼여료배합물적공간련접．
： By the way of solvent synthesis, a new Mn polymer was prepared, [Mn（TBDZ）z] NO3·Cl. H2O[TBDZ= thiabendazole]. This polymer belongs to monoclinic and its group space is P2 （1）/c, a = 16. 003（7）A, b =11.158（5）.A c =13.905（6）A, a =90.00°, 8=113.196（5）°, γ=90.00°, V=2282.3（16）Aa, Z =4. Each Manganese ion build double chelate structures with two Nitrogen atoms from thiabendazole, it also coordinated with a chloride ion and an oxygen atom from water. Which help Mn ion to build a deformation of the octahedral tructure. The uncoordinated nitrate ion joined the connection of polymer space by building two hydrogen bonds with a hydrogen from water and a hydrogen from imino which lies on thiaben-dazole.