宝石和宝石学杂志
寶石和寶石學雜誌
보석화보석학잡지
Journal of Gems & gemmology
2012年
2期
13-18
,共6页
杨晔%陈美华%隗澎%胡葳
楊曄%陳美華%隗澎%鬍葳
양엽%진미화%외팽%호위
合成翡翠%溶胶-凝胶法%高温高压处理
閤成翡翠%溶膠-凝膠法%高溫高壓處理
합성비취%용효-응효법%고온고압처리
synthetic jadeite%sol-gel technique%HTHP
采用溶胶-凝胶法合成具有翡翠成分的玻璃料,再对其进行高温高压处理,实现玻璃体向晶质硬玉的转化,从而得到合成翡翠。从金属醇盐浓度、pH值、去离子水的添加量、水浴温度四个方面探讨了最佳凝胶条件。常规宝石学特征测试、偏光显微镜下岩矿薄片分析、X射线粉末衍射和傅里叶变换红外光谱表明,合成翡翠与天然翡翠的常规宝石学性质相近,其结晶矿物为硬玉,样品的结晶转化程度较好,具有硬玉的标准红外特征吸收峰。
採用溶膠-凝膠法閤成具有翡翠成分的玻璃料,再對其進行高溫高壓處理,實現玻璃體嚮晶質硬玉的轉化,從而得到閤成翡翠。從金屬醇鹽濃度、pH值、去離子水的添加量、水浴溫度四箇方麵探討瞭最佳凝膠條件。常規寶石學特徵測試、偏光顯微鏡下巖礦薄片分析、X射線粉末衍射和傅裏葉變換紅外光譜錶明,閤成翡翠與天然翡翠的常規寶石學性質相近,其結晶礦物為硬玉,樣品的結晶轉化程度較好,具有硬玉的標準紅外特徵吸收峰。
채용용효-응효법합성구유비취성분적파리료,재대기진행고온고압처리,실현파리체향정질경옥적전화,종이득도합성비취。종금속순염농도、pH치、거리자수적첨가량、수욕온도사개방면탐토료최가응효조건。상규보석학특정측시、편광현미경하암광박편분석、X사선분말연사화부리협변환홍외광보표명,합성비취여천연비취적상규보석학성질상근,기결정광물위경옥,양품적결정전화정도교호,구유경옥적표준홍외특정흡수봉。
In this paper, the mechanism of synthetic jadeite is investigated by sol-gel tech- nique. The best gelation factors are studied from metal alcoholate concentration, pH value, amount of ionized water and water-bath temperature. The results of gemmological characteristics tests, polarizing microscope, X-ray powder diffraction and infrared spectrometer show that the gemmological characteristics of the synthetic jadeite are similar to those of the natu ral jadeite, and that the main crystal phase of synthetic jadeite is jadeite. The crystalline coversion of the sample is also very good. The sample of HTHP synthetic jadeite has the same characterized infrared absorption peaks as that of jadeite.