高电压技术
高電壓技術
고전압기술
HIGH VOLTAGE ENGINEERING
2012年
5期
1106-1113
,共8页
柳晶晶%Kong Michael G
柳晶晶%Kong Michael G
류정정%Kong Michael G
He和N2辉光放电%双向拉伸聚丙烯(BOPP)表面改性%粘附性实验%亲水性%活性化学功能团%表面结构
He和N2輝光放電%雙嚮拉伸聚丙烯(BOPP)錶麵改性%粘附性實驗%親水性%活性化學功能糰%錶麵結構
He화N2휘광방전%쌍향랍신취병희(BOPP)표면개성%점부성실험%친수성%활성화학공능단%표면결구
He and N2 glow discharge%biaxially oriented polypropylene(BOPP) surface modification%attachment experiment%hydrophilieity%functional groups%surface morphology
生物用薄膜双向拉伸聚丙烯(BOPP)表面的惰性特性影响了其更为广泛的应用,为解决这一问题,需要在不改变薄膜主体特性的情况下对其表面特性进行改性。采用大气压下He和N2辉光放电等离子体对该薄膜进行了表面改性,并研究了等离子体各种参数对表面改性的影响。通过对该等离子体放电特性和光谱特性的研究,验证了其低温和均匀特性。大肠杆菌E.coli K12在等离子体处理后的BOPP表面的粘附性实验表明,N2体积流量和处理时间对BOPP表面改性有重要影响,加入N2的等离子体能提升BOPP膜表面的细菌粘附性。为进一步研究等离子体BOPP表面改性的机理,对等离子体处理后的BOPP进行了接触角测量、X射线光电子能谱(XPS)、原子力显微镜(AFM)分析。分析表明,等离子体改性后薄膜的亲水性、活性化学功能团、表面结构发生了显著变化。
生物用薄膜雙嚮拉伸聚丙烯(BOPP)錶麵的惰性特性影響瞭其更為廣汎的應用,為解決這一問題,需要在不改變薄膜主體特性的情況下對其錶麵特性進行改性。採用大氣壓下He和N2輝光放電等離子體對該薄膜進行瞭錶麵改性,併研究瞭等離子體各種參數對錶麵改性的影響。通過對該等離子體放電特性和光譜特性的研究,驗證瞭其低溫和均勻特性。大腸桿菌E.coli K12在等離子體處理後的BOPP錶麵的粘附性實驗錶明,N2體積流量和處理時間對BOPP錶麵改性有重要影響,加入N2的等離子體能提升BOPP膜錶麵的細菌粘附性。為進一步研究等離子體BOPP錶麵改性的機理,對等離子體處理後的BOPP進行瞭接觸角測量、X射線光電子能譜(XPS)、原子力顯微鏡(AFM)分析。分析錶明,等離子體改性後薄膜的親水性、活性化學功能糰、錶麵結構髮生瞭顯著變化。
생물용박막쌍향랍신취병희(BOPP)표면적타성특성영향료기경위엄범적응용,위해결저일문제,수요재불개변박막주체특성적정황하대기표면특성진행개성。채용대기압하He화N2휘광방전등리자체대해박막진행료표면개성,병연구료등리자체각충삼수대표면개성적영향。통과대해등리자체방전특성화광보특성적연구,험증료기저온화균균특성。대장간균E.coli K12재등리자체처리후적BOPP표면적점부성실험표명,N2체적류량화처리시간대BOPP표면개성유중요영향,가입N2적등리자체능제승BOPP막표면적세균점부성。위진일보연구등리자체BOPP표면개성적궤리,대등리자체처리후적BOPP진행료접촉각측량、X사선광전자능보(XPS)、원자력현미경(AFM)분석。분석표명,등리자체개성후박막적친수성、활성화학공능단、표면결구발생료현저변화。
The inert surface nature of hi-axially oriented polypropylene (BOPP) prevents its wider applications, so it is desirable to tailor its surface properties without affecting its bulk property. BOPP was modified by atmospheric pressure He and N2 glow discharge. The effect of plasma parameters on the surface modification was investigated. Moreover, the electrical and optical characteristics were studied, indicating that plasmas were low temperature and uniform. The experiment of the attachment of E. coli K12 on the plasma treated BOPP was conducted, showing that N2 flowing rate and treatment time had significant influence on the BOPP surface modification, the attachment of E. coli K12 could be improved by plasmas with adding N2. Contact angle measurement, X-ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM) were adopted to analyze the polymer surface. It is shown that the hydrophilicity, functional groups and surface morphology of the BOPP surface are significantly modified by the plasmas.