广东化工
廣東化工
엄동화공
GUANGDONG CHEMICAL INDUSTRY
2012年
6期
94-95
,共2页
配体%温控相转移催化%氢甲酰化%烯烃加氢%均相催化剂分离
配體%溫控相轉移催化%氫甲酰化%烯烴加氫%均相催化劑分離
배체%온공상전이최화%경갑선화%희경가경%균상최화제분리
ligands%thermoregulated phase-transfer catalysis%hydroformylation%homogeneous catalysts separation
综述了水/有机两相＂温控相转移催化＂的原理,在此基础上设计、合成了以非离子型水溶性膦配体和两性双吡啶配体,并与过渡金属络合制备出温控相转移催化剂。综述了其在水/有机两相CO还原,烯烃加氢和Heck反应中的应用效果。
綜述瞭水/有機兩相＂溫控相轉移催化＂的原理,在此基礎上設計、閤成瞭以非離子型水溶性膦配體和兩性雙吡啶配體,併與過渡金屬絡閤製備齣溫控相轉移催化劑。綜述瞭其在水/有機兩相CO還原,烯烴加氫和Heck反應中的應用效果。
종술료수/유궤량상＂온공상전이최화＂적원리,재차기출상설계、합성료이비리자형수용성련배체화량성쌍필정배체,병여과도금속락합제비출온공상전이최화제。종술료기재수/유궤량상CO환원,희경가경화Heck반응중적응용효과。
The principle of the thermoregulated phase-transfer catalysis;the design and synthesis of thermoregulated phase-transfer ligands and the amphiphilic dipyridyl-based ligand,then preparation of thermoregulated phase-transfer catalyst by complex with the transition metal.Their application in the water/organic two CO reduction,olefin hydrogenation Heck reaction,were systematically introduced.
