广东化工
廣東化工
엄동화공
GUANGDONG CHEMICAL INDUSTRY
2012年
6期
23-24
,共2页
非离子型表面活性剂%微乳液%结构参数
非離子型錶麵活性劑%微乳液%結構參數
비리자형표면활성제%미유액%결구삼수
nonionic surfactant%microemulsion%structural parameter
采用非离子表面活性剂吐温-80,以石油醚为油相,正丁醇为助表面活性剂来制备微乳液。用稀释法测定并计算了Tween-80/石油醚/正丁醇/水体系O/W型微乳的结构参数。测量微乳液体系在15~30℃温度范围内的pH及电导,考察温度对微乳液体系的影响。向微乳液体系中加入PVP,测量体系的电导和接触角,考察水溶性高分子对微乳液体系的影响。结果表明微乳液体系的电导随温度的上升而变大,相同温度时,加入PVP会使体系的电导变大,接触角变小。
採用非離子錶麵活性劑吐溫-80,以石油醚為油相,正丁醇為助錶麵活性劑來製備微乳液。用稀釋法測定併計算瞭Tween-80/石油醚/正丁醇/水體繫O/W型微乳的結構參數。測量微乳液體繫在15~30℃溫度範圍內的pH及電導,攷察溫度對微乳液體繫的影響。嚮微乳液體繫中加入PVP,測量體繫的電導和接觸角,攷察水溶性高分子對微乳液體繫的影響。結果錶明微乳液體繫的電導隨溫度的上升而變大,相同溫度時,加入PVP會使體繫的電導變大,接觸角變小。
채용비리자표면활성제토온-80,이석유미위유상,정정순위조표면활성제래제비미유액。용희석법측정병계산료Tween-80/석유미/정정순/수체계O/W형미유적결구삼수。측량미유액체계재15~30℃온도범위내적pH급전도,고찰온도대미유액체계적영향。향미유액체계중가입PVP,측량체계적전도화접촉각,고찰수용성고분자대미유액체계적영향。결과표명미유액체계적전도수온도적상승이변대,상동온도시,가입PVP회사체계적전도변대,접촉각변소。
We selected tween-80,petroleum ether,and n-butanol as nonionic surfactant,oil phase and cosurfactant,repectively,and prepared the microemulsions.The structural parameters of O/W microemulsion system of tween-80/petroleum ether/n-butanol/water were measured by dilution method and calculated based on the sphere model.The pH and conductance of the system were also measured during the temperature from 15 to 30 ℃.The effects of the temperature on the microemulsions were discussed in detail.On the second hand,we added the water-soluble polymer,poly(vinyl pyrrolidone)(PVP) into the system.At the same time,the effects of water-soluble polymer on the microemulsion were conducted by measuring the electric conductance and contact angle.The results showed that the electric conductance increases along with the temperature rise,the electric conductance increased but the contact angle reduces by the adding of PVP at room temperature.