山东化工
山東化工
산동화공
SHANDONG CHEMICAL INDUSTRY
2012年
7期
11-14
,共4页
凌静%何少华%夏勇锋%林振波
凌靜%何少華%夏勇鋒%林振波
릉정%하소화%하용봉%림진파
十二烷基磺酸钠改性硅藻土%Cd2+%吸附
十二烷基磺痠鈉改性硅藻土%Cd2+%吸附
십이완기광산납개성규조토%Cd2+%흡부
twelve sodium dodecyl sulfate modified diatomite%Cd2+ adsorption
用十二烷基磺酸钠对天然硅藻土进行改性,改性后硅藻土的吸附效果明显优于天然硅藻土,吸附量由4.973mg/g增加到17.045mg/g。通过静态吸附实验探讨了改性硅藻土对废水中Cd2+的吸附主要影响因素和动力学。在本实验条件下,吸附量随温度与Cd2+浓度的增加而增加,但随改性硅藻土用量的增加而减少。在pH值为3~6时,吸附量随pH值的增加而增加。吸附动力学符合Imgergren准二级方程。
用十二烷基磺痠鈉對天然硅藻土進行改性,改性後硅藻土的吸附效果明顯優于天然硅藻土,吸附量由4.973mg/g增加到17.045mg/g。通過靜態吸附實驗探討瞭改性硅藻土對廢水中Cd2+的吸附主要影響因素和動力學。在本實驗條件下,吸附量隨溫度與Cd2+濃度的增加而增加,但隨改性硅藻土用量的增加而減少。在pH值為3~6時,吸附量隨pH值的增加而增加。吸附動力學符閤Imgergren準二級方程。
용십이완기광산납대천연규조토진행개성,개성후규조토적흡부효과명현우우천연규조토,흡부량유4.973mg/g증가도17.045mg/g。통과정태흡부실험탐토료개성규조토대폐수중Cd2+적흡부주요영향인소화동역학。재본실험조건하,흡부량수온도여Cd2+농도적증가이증가,단수개성규조토용량적증가이감소。재pH치위3~6시,흡부량수pH치적증가이증가。흡부동역학부합Imgergren준이급방정。
Natural diatomite was modified by twelve sodium dodecyl sulfate and the adsorption effects of modified diatomite were better than natural diatomite. The adsorption quantity from 4.973mg/g increased to 17. 045mg/g. The mainly affecting factors and the kinetics hade been investigated under through batch experinents of adsorbing Cd2+ in wastewater by modified diatomite. Under the experiment conditions, the adsorption capacity was increased with the increasing temperature and the Cd2 + initial concentration. But the adsorption capacity was decreased with the increasing amounts of modified diatomite. When pH was between 3 and 6, the adsorption capacity was increasd with increasing pH. The adsorption kinetics fitted well to the Lagergren psedo -second order equation.