中国烟草科学
中國煙草科學
중국연초과학
CHINESE TOBACCO SCIENCE
2013年
6期
108-112
,共5页
于宏晓%赵砚棠%董永智%赵华民%王正峰%王青海%马强%徐海涛%米强%赵国庆
于宏曉%趙硯棠%董永智%趙華民%王正峰%王青海%馬彊%徐海濤%米彊%趙國慶
우굉효%조연당%동영지%조화민%왕정봉%왕청해%마강%서해도%미강%조국경
碳空心材料%主流烟气%酚类物质
碳空心材料%主流煙氣%酚類物質
탄공심재료%주류연기%분류물질
carbon hollow material%mainstream smoke%phenolic compounds
为了降低卷烟主流烟气中酚类有害成分，以乙醇、环己醇、聚乙二醇400和聚乙二醇600不同醇类为原料与草酸亚铁反应制备了不同碳空心材料，利用傅里叶变换红外光谱（FTIR）、扫描电子显微镜（SEM）、比表面及孔径分析仪对其进行了表征，并分别考察了添加不同碳空心材料的复合滤嘴对卷烟主流烟气中酚类有害成分释放量的影响。结果表明，碳空心材料具有优异的吸附性能，其对主流烟气中邻苯二酚、间苯二酚、对苯二酚、苯酚、邻甲酚、间甲酚和对甲酚酚类有害成分有良好的吸附能力。尤其乙醇制备的碳空心材料吸附酚类有害成分的能力最高，其吸附能力比活性炭材料高，对主流烟气中主要酚类有害成分吸附率达到50%以上，能够明显降低主流烟气中酚类有害成分。
為瞭降低捲煙主流煙氣中酚類有害成分，以乙醇、環己醇、聚乙二醇400和聚乙二醇600不同醇類為原料與草痠亞鐵反應製備瞭不同碳空心材料，利用傅裏葉變換紅外光譜（FTIR）、掃描電子顯微鏡（SEM）、比錶麵及孔徑分析儀對其進行瞭錶徵，併分彆攷察瞭添加不同碳空心材料的複閤濾嘴對捲煙主流煙氣中酚類有害成分釋放量的影響。結果錶明，碳空心材料具有優異的吸附性能，其對主流煙氣中鄰苯二酚、間苯二酚、對苯二酚、苯酚、鄰甲酚、間甲酚和對甲酚酚類有害成分有良好的吸附能力。尤其乙醇製備的碳空心材料吸附酚類有害成分的能力最高，其吸附能力比活性炭材料高，對主流煙氣中主要酚類有害成分吸附率達到50%以上，能夠明顯降低主流煙氣中酚類有害成分。
위료강저권연주류연기중분류유해성분，이을순、배기순、취을이순400화취을이순600불동순류위원료여초산아철반응제비료불동탄공심재료，이용부리협변환홍외광보（FTIR）、소묘전자현미경（SEM）、비표면급공경분석의대기진행료표정，병분별고찰료첨가불동탄공심재료적복합려취대권연주류연기중분류유해성분석방량적영향。결과표명，탄공심재료구유우이적흡부성능，기대주류연기중린분이분、간분이분、대분이분、분분、린갑분、간갑분화대갑분분류유해성분유량호적흡부능력。우기을순제비적탄공심재료흡부분류유해성분적능력최고，기흡부능력비활성탄재료고，대주류연기중주요분류유해성분흡부솔체도50%이상，능구명현강저주류연기중분류유해성분。
In order to reduce harmful phenolic ingredients in the mainstream smoke, different carbon hollow materials were synthesized through ferrous oxalate with ethanol, cyclohexanol, polyethylene glycol 400 and polyethylene glycol 600, respectively. These different carbon hollow materials were characterized via Fourier Transform Infrared Spectroscopy(FTIR), Scanning Electron Microscopy(SEM) and BET specific surface area analyzer. These materials were applied in composite filter for testing the removal efficiency for phenolic compounds. The results showed that these carbon hollow materials had excellent adsorption capability for catechol, resorcinol, hydroquinone, phenol, o-cresol, m-cresol and cresol phenolic harmful ingredients in the mainstream smoke. The adsorption capability of carbon hollow material prepared from ethanol was much higher than those of other samples and activated carbon material. The adsorption efficiency of carbon hollow material prepared from ethanol was more than 50%for phenolic harmful ingredients and it could significantly reduce the phenolic harmful ingredients in the mainstream smoke.
