中国材料进展
中國材料進展
중국재료진전
MATERIALS CHINA
2012年
8期
47-51
,共5页
邵鑫%刘凤珍%孙巧珍%孟宪华%刘雪华
邵鑫%劉鳳珍%孫巧珍%孟憲華%劉雪華
소흠%류봉진%손교진%맹헌화%류설화
水热%YY2O3:Eu^3+%PEG-2000%发光
水熱%YY2O3:Eu^3+%PEG-2000%髮光
수열%YY2O3:Eu^3+%PEG-2000%발광
hydrothermal%Y2O3 : Eu^3+%PEG-2000%luminescence
以NaOH,Y(NO3)3·6H2O和Eu(NO3)3.6H2O为前驱体,通过添加络合剂PEG-2000,采用水热法,成功地合成了Y2O3:Eu^3+纳米棒和纳米管,并采用先进的测试手段对其结构和性能进行了表征与测试。探讨了Y2O3:Eu^3+纳米棒和纳米管的生长机制,同时研究了Y2O3:Eu^3+纳米晶的光致发光性能。研究结果表明,水热温度、反应时间、NaOH的添加量和PEG-2000对产物形貌有着非常重要的影响,所制备的材料具有Eu^3+的特征红光发射,并在Eu^3+的掺杂量为5%(摩尔分数)时样品发光最好。
以NaOH,Y(NO3)3·6H2O和Eu(NO3)3.6H2O為前驅體,通過添加絡閤劑PEG-2000,採用水熱法,成功地閤成瞭Y2O3:Eu^3+納米棒和納米管,併採用先進的測試手段對其結構和性能進行瞭錶徵與測試。探討瞭Y2O3:Eu^3+納米棒和納米管的生長機製,同時研究瞭Y2O3:Eu^3+納米晶的光緻髮光性能。研究結果錶明,水熱溫度、反應時間、NaOH的添加量和PEG-2000對產物形貌有著非常重要的影響,所製備的材料具有Eu^3+的特徵紅光髮射,併在Eu^3+的摻雜量為5%(摩爾分數)時樣品髮光最好。
이NaOH,Y(NO3)3·6H2O화Eu(NO3)3.6H2O위전구체,통과첨가락합제PEG-2000,채용수열법,성공지합성료Y2O3:Eu^3+납미봉화납미관,병채용선진적측시수단대기결구화성능진행료표정여측시。탐토료Y2O3:Eu^3+납미봉화납미관적생장궤제,동시연구료Y2O3:Eu^3+납미정적광치발광성능。연구결과표명,수열온도、반응시간、NaOH적첨가량화PEG-2000대산물형모유착비상중요적영향,소제비적재료구유Eu^3+적특정홍광발사,병재Eu^3+적참잡량위5%(마이분수)시양품발광최호。
Highly uniform and monodisperse Y2O3 : Eu^3+ nanorods and nanotubes were successfully prepared in large quantities using a facile hydrothermal approach assisted by a capping reagent, PEG-2000. Cheaper NaOH, Y( NO3 ) 3·6H2O and Eu( NO3 )3 · 6H2O were used as the raw materials. The formation mechanism of Y2O3 : Eu^3+ nanorods and nanotubes were discussed. The results showed that the morphologies of Y2O3 : Eu^3+ were depended on the different reaction temperatures, reaction time, the addition of NaOH and PEG-2000, and the prepared material had characteristic red emission of Eu^3+ , while identifying 5% Eu^3+ -doped Y203 had the best property of luminescence.