CAJ | 학술논문

以超纯水为提取溶剂,采用甲醇-0.02 mol/L乙酸铵溶液的流动相体系和负离子电离模式,用超高效液相色谱-三重四极杆质谱联用仪测定白酒中的安赛蜜、糖精钠、甜蜜素和三氯蔗糖。结果表明,安赛蜜、糖精钠、甜蜜素和三氯蔗糖线性范围在10～1000 ng/mL内R2大于0.9983,检出限分别为0.024 mg/kg、0.06 mg/kg、0.03 mg/kg、0.1 mg/kg,加标回收率大于82%,RSD小于2.01%。该方法简便灵敏,准确快速,可用于白酒中微量甜味剂的快速测定。
이초순수위제취용제,채용갑순-0.02 mol/L을산안용액적류동상체계화부리자전리모식,용초고효액상색보-삼중사겁간질보련용의측정백주중적안새밀、당정납、첨밀소화삼록자당。결과표명,안새밀、당정납、첨밀소화삼록자당선성범위재10～1000 ng/mL내R2대우0.9983,검출한분별위0.024 mg/kg、0.06 mg/kg、0.03 mg/kg、0.1 mg/kg,가표회수솔대우82%,RSD소우2.01%。해방법간편령민,준학쾌속,가용우백주중미량첨미제적쾌속측정。
A fast and accurate method for the determination of sweeteners content in liquor had been developed. Liquor samples were extracted by pure water and the content of aeesulfame-K, saccharin sodium, cyclamate, and sucralose in liquor were determined by ultra performance liquid chromatography-tandem mass spectrometry （UPLC-MS/MS）. The calibration curve of these four compounds showed a good linearity in the range of 10.0- 1000 ng/mL, and the correlation coefficients were better than 0.9983. The limits of detection （LODS） of the method were 0.024 mg/kg for acesulfame-K, 0.06 mg/kg for saccharin sodium, 0.03 mg/kg for cyclamate and 0.1 mg/kg for sucralose, respectively. The average recoveries were higher than 82 % and the relative standard deviations （RSD） of the method were lower than 2.01%.