CAJ | 학술논문

以甲基丙烯酸甲酯（MMA）、丙烯酸丁酯（BA）和甲基丙烯酸（MAA）为单体，采用梯度乳液聚合法制备了水性丙烯酸酯乳液，并以聚磷酸铵（斛’）一季戊四醇（PER）．三聚氰胺（衄。）为协同阻燃体系，以长余辉发光材料为储能发光物质，制备了一种环保水性发光防火涂料。结果表明，乳液合成配方中的不同单体配比对合成乳液的成膜性能有很大影响。mAPP：mPER：mMEL=7：3：4时，配制的涂料具有较好的防火阻燃性能；向防火涂料中引入长余辉发光粉后，所得产品耐酒精喷灯燃烧时间可达18min，防火等级为一级，且具有一定的光致发光功能。
이갑기병희산갑지（MMA）、병희산정지（BA）화갑기병희산（MAA）위단체，채용제도유액취합법제비료수성병희산지유액，병이취린산안（곡’）일계무사순（PER）．삼취청알（뉵。）위협동조연체계，이장여휘발광재료위저능발광물질，제비료일충배보수성발광방화도료。결과표명，유액합성배방중적불동단체배비대합성유액적성막성능유흔대영향。mAPP：mPER：mMEL=7：3：4시，배제적도료구유교호적방화조연성능；향방화도료중인입장여휘발광분후，소득산품내주정분등연소시간가체18min，방화등급위일급，차구유일정적광치발광공능。
Using methyl methacrylate （MMA）, butyl acrylate （BA） and methacrylic acid （MAA） as mono- mers, the aqueous acrylic ester emulsion was synthesized by adopting gradient emulsion polymerization. The environmentally-friendly water-based luminescent fire-retardant coating was prepared by using ammonium polyphosphate（APP）-pentaerythritol（PER）-melamine（MEL） as synergistic fire-retardant system and using long afterglow luminescent material as energy storage luminescent substance. The results show that the different monomers＇ ratios in the synthesis formulation have great effect on the film-forming properties of the synthesized emulsion; the prepared coating has excellent fire-retardant property when mApp： mCER： mMEL = 7：3：4;after the introduction of long afterglow luminescence powder, the fire-resistant time of the obtained fire-retardant coating gets to 18 min, and the product has Grade One fire-resistant property; at the same time, it has a certain photoluminescence property.