琼州学院学报
瓊州學院學報
경주학원학보
JOURNAL OF QIONGZHOU UNIVERSITY
2012年
2期
8-10
,共3页
1,1'-(1,4-丁基)二咪唑%自组装%配合物
1,1'-(1,4-丁基)二咪唑%自組裝%配閤物
1,1'-(1,4-정기)이미서%자조장%배합물
1,1' - ( 1,4 - butanediyl) bis (imidazole)%self - assembly%coordination polymer
通过金属盐和1,1'-(1,4-丁基)二咪唑(L)进行自组装得到了一个新颖的配合物[ZnLCl2],并进行了该配体的晶体结构测定。在该化合物中,每个锌离子与两个氯离子和来自L的两个氮原子配位。L桥连两个锌离子,形成Z字形链状结构。
通過金屬鹽和1,1'-(1,4-丁基)二咪唑(L)進行自組裝得到瞭一箇新穎的配閤物[ZnLCl2],併進行瞭該配體的晶體結構測定。在該化閤物中,每箇鋅離子與兩箇氯離子和來自L的兩箇氮原子配位。L橋連兩箇鋅離子,形成Z字形鏈狀結構。
통과금속염화1,1'-(1,4-정기)이미서(L)진행자조장득도료일개신영적배합물[ZnLCl2],병진행료해배체적정체결구측정。재해화합물중,매개자리자여량개록리자화래자L적량개담원자배위。L교련량개자리자,형성Z자형련상결구。
A new coordination polymer [ ZnLCI2 ] was obatained from self - assembly of the corresponding met- al salt with 1,1' - ( 1,4 - butanediyl) bis (imidazole) (L) and its structure was determined by X - ray diffraction method. In the complex, each zinc ion is coordinated to two nitrogen atoms from two molecules of L, and to two chlorine ions. Each L molecule is coordinated to two zinc ions, acting as a bridging ligand . The bridged zinc ions form an zigzag chain structure.