CAJ | 학술논문

采用化学镀方法在SiO2/Si 基底上制备Cu互联线用阻挡层材料Ni-Mo-P薄膜。采用场发射扫描电子显微镜、电子分散能谱仪、原子力显微镜分析不同沉积时间样品的表面形貌和成分，并对Ni-Mo-P薄膜的形成过程进行研究。Ni-Mo-P薄膜的形成过程分为3个阶段：催化阶段，先前还原的Pd颗粒成为Ni还原的催化形核中心，诱导Ni沉积；覆盖阶段，Ni颗粒诱导Mo、P与之进行共沉积；自生长阶段，Ni-Mo-P薄膜共同沉积，颗粒生长。阐述了还原剂被氧化后产物为3-4PO 的的反应机理。
채용화학도방법재SiO2/Si 기저상제비Cu호련선용조당층재료Ni-Mo-P박막。채용장발사소묘전자현미경、전자분산능보의、원자력현미경분석불동침적시간양품적표면형모화성분，병대Ni-Mo-P박막적형성과정진행연구。Ni-Mo-P박막적형성과정분위3개계단：최화계단，선전환원적Pd과립성위Ni환원적최화형핵중심，유도Ni침적；복개계단，Ni과립유도Mo、P여지진행공침적；자생장계단，Ni-Mo-P박막공동침적，과립생장。천술료환원제피양화후산물위3-4PO 적적반응궤리。
The diffusion barrier Ni-Mo-P film for Cu interconnects was prepared on SiO2/Si substrate using electroless method. The surface morphology and composition during the formation process of electroless Ni-Mo-P film were investigated through analyzing samples of different deposition time. Induced nucleation, induced co-deposition, and self-induced growth mechanisms involved in electroless process were confirmed by field-emission scanning electron microscopy (FE-SEM), energy dispersive spectrometry and atomic force microscopy (AFM). Firstly, the preceding palladium particles as catalysts induce the nucleation of nickel. Secondly, the nickel particles induce the deposition of molybdenum and phosphorus, which attributes to induced co-deposition. Thirdly, former deposited Ni-Mo-P induces deposition of the latter Ni-Mo-P particles. Moreover, the reaction mechanism was proposed with the oxydate of 3-4PO .