兵器材料科学与工程
兵器材料科學與工程
병기재료과학여공정
Ordnance Material Science and Engineering
2013年
4期
6-9
,共4页
李兆%江元汝%徐克%赵西成%赵亚娟
李兆%江元汝%徐剋%趙西成%趙亞娟
리조%강원여%서극%조서성%조아연
氧化铝粉体%水热-热解%形貌控制%YAG荧光粉
氧化鋁粉體%水熱-熱解%形貌控製%YAG熒光粉
양화려분체%수열-열해%형모공제%YAG형광분
alumina powder%hydrothermal-pyrolysis%morphology control%YAG phosphors
3~5μm的片状α-Al2O3是白光LED用荧光粉的良好基材。采用水热-热解法控制合成出不同形貌α-Al2O3粉体。以自制的3种形貌氧化铝及市售Y2O3,Ce2O3为原料,AlF3为助溶剂,采用高温固相法合成钇铝石榴石(YAG:Ce3+)黄色荧光粉。结果表明,通过控制不同的添加剂,控制反应条件,可以实现对α-Al2O3粉体形貌和粒径的控制。
3~5μm的片狀α-Al2O3是白光LED用熒光粉的良好基材。採用水熱-熱解法控製閤成齣不同形貌α-Al2O3粉體。以自製的3種形貌氧化鋁及市售Y2O3,Ce2O3為原料,AlF3為助溶劑,採用高溫固相法閤成釔鋁石榴石(YAG:Ce3+)黃色熒光粉。結果錶明,通過控製不同的添加劑,控製反應條件,可以實現對α-Al2O3粉體形貌和粒徑的控製。
3~5μm적편상α-Al2O3시백광LED용형광분적량호기재。채용수열-열해법공제합성출불동형모α-Al2O3분체。이자제적3충형모양화려급시수Y2O3,Ce2O3위원료,AlF3위조용제,채용고온고상법합성을려석류석(YAG:Ce3+)황색형광분。결과표명,통과공제불동적첨가제,공제반응조건,가이실현대α-Al2O3분체형모화립경적공제。
The flake Al2O3 powder with a particle size of 3-5 μm is a good base for white LED phosphor powder. α?Al2O3 powder with different morphologies was produced by hydrothermal ? pyrolysis method. The yellow phosphor powder YAG:Ce3 + was synthesized by the high temperature solid state method with the self ? made alumina in three different morphologies and the commercial Y2O3,Ce2O3 as raw materials and aluminum fluoride as cosolvent. The result indicates that the morphology and particle size of Al2O3 powder could be controlled by changing the amount of additives and reaction conditions.