石家庄学院学报
石傢莊學院學報
석가장학원학보
JOURNAL OF SHIJIAZHUANG COLLEGE
2012年
3期
5-8
,共4页
β-环糊精有机酸包合物%电流变材料%电流变性能
β-環糊精有機痠包閤物%電流變材料%電流變性能
β-배호정유궤산포합물%전류변재료%전류변성능
β-cyclodextrin%inclusion compound%organic acid%electrorheological material%electrorheological performance
用β-环糊精(简称β-CD)、对甲苯磺酸、磺基水杨酸、对氨基苯磺酸、对苯二甲酸、α-萘乙酸和2,6-吡啶二羧酸为原料,采用固相反应,合成了新型的电流变材料——以β-环糊精为主体、磺基水杨酸等有机酸为客体的包合物. 研究了材料的组成结构与材料电流变性能的关系. 结果表明:包合对甲苯磺酸和磺基水杨酸可以明显的提高主体β-环糊精的电流变性能,β-环糊精与磺基水杨酸的包合物有最高的电流变活性.
用β-環糊精(簡稱β-CD)、對甲苯磺痠、磺基水楊痠、對氨基苯磺痠、對苯二甲痠、α-萘乙痠和2,6-吡啶二羧痠為原料,採用固相反應,閤成瞭新型的電流變材料——以β-環糊精為主體、磺基水楊痠等有機痠為客體的包閤物. 研究瞭材料的組成結構與材料電流變性能的關繫. 結果錶明:包閤對甲苯磺痠和磺基水楊痠可以明顯的提高主體β-環糊精的電流變性能,β-環糊精與磺基水楊痠的包閤物有最高的電流變活性.
용β-배호정(간칭β-CD)、대갑분광산、광기수양산、대안기분광산、대분이갑산、α-내을산화2,6-필정이최산위원료,채용고상반응,합성료신형적전류변재료——이β-배호정위주체、광기수양산등유궤산위객체적포합물. 연구료재료적조성결구여재료전류변성능적관계. 결과표명:포합대갑분광산화광기수양산가이명현적제고주체β-배호정적전류변성능,β-배호정여광기수양산적포합물유최고적전류변활성.
A novel type of electrorheological(ER) materials,the inclusion compounds between β-cyclodextrin(β-CD) as the subject,and organic acids as the objects are synthesized using β-CD,p-toluenesulfonic acid,sulfosalicylic acid,p-aminobenzenesulfonic acid,terephthalic acid,a-naphthylacetic acid and 2,6-dipicolinic acid as original materials by a solid reaction.The relationships between ER performance of the materials and their composition structures are studied.The results show that p-toluenesulfonic acid or sulfosalicylic acid as the guest can enhance obviously the ER performance of β-CD as the subject.The inclusion compound between β-CD and sulfosalicylic acid has the highest ER activity.