CAJ | 학술논문

制备了硫酸促进型酯化催化剂SO42-/WO3-ZrO2,考察了WO3含量、焙烧温度和焙烧时间等对酯化率的影响。结果表明催化剂适宜制备条件为：WO3含量10%,300℃焙烧2h;将其用于催化乙酸与正丁醇的酯化反应合成了乙酸丁酯,反应条件为：乙酸0.2mol,催化剂0.75g,n（正丁醇）∶n（乙酸）=1.8∶1,反应时间30min,酯化率可达98.2%。
제비료류산촉진형지화최화제SO42-/WO3-ZrO2,고찰료WO3함량、배소온도화배소시간등대지화솔적영향。결과표명최화제괄의제비조건위：WO3함량10%,300℃배소2h;장기용우최화을산여정정순적지화반응합성료을산정지,반응조건위：을산0.2mol,최화제0.75g,n（정정순）∶n（을산）=1.8∶1,반응시간30min,지화솔가체98.2%。
To prepare the esterification catalyst SO42-/WO3-ZrO2, investigate the effects of various factors such as preparative conditions of the catalyst. The results showed that with concentration of WO3 10 %,caIcinating at 300℃ for 2.0 h. Butyl acetate was synthesized with the catalyst. The optimized conditions were acetic acid 0.2 mol, mole ratio of alcohol to acid 1.8 ： 1 ,reaction time 30 rain and catalyst dosage 0.75 g,esterification rate is 98.2%.