CAJ | 학술논문

利用X-射线光电子能谱（XPS）分析掺杂元素对二氧化钛中O1s和Ti2p的结合能峰的变化。从实验数据求出△（O-Ti）值,分析变化的原因。数据显示：共掺杂后△（O-Ti）的值的变化范围为71.2～71.5 eV之间,掺杂后△（O-Ti）值大于纯TiO2。可见光光催化氧化4-氯苯酚结果表明：随着△（O-Ti）值的增大,可见光光催化活性逐步提高。
이용X-사선광전자능보（XPS）분석참잡원소대이양화태중O1s화Ti2p적결합능봉적변화。종실험수거구출△（O-Ti）치,분석변화적원인。수거현시：공참잡후△（O-Ti）적치적변화범위위71.2～71.5 eV지간,참잡후△（O-Ti）치대우순TiO2。가견광광최화양화4-록분분결과표명：수착△（O-Ti）치적증대,가견광광최화활성축보제고。
The changes of binding energies for O1 s and Ti2p in codoping titanium dioxides were analyzed using X - ray photoelectron spectroscopy （XPS）. The binding energy difference A （O -Ti） was calculated by a set of available ex- perimental data on the binding energies of Ti2p3/2 and O1 s core levels and the reasons were summarized. The data presen- ted that the a （O -Ti）was in range of 71.2 -71.5 eV, and was larger than that of pure TiO2. The results showed that the visible light photocatalytic performances were enhanced with enhancing of a （O -Ti）.