CAJ | 학술논문

为有效的提高聚乙烯醇（polyvinyl alcohol，PVA）的成膜后阻湿性能，该研究采用乳化剂聚甘油酯和单甘酯复配乳化蜂蜡使其与PVA形成稳定的乳液。在PVA基膜材料中添加了蜂蜡及纳米α-Fe2O3，利用单因素试验确定了响应曲面试验的因素水平，从而使用响应面试验研究了两者之间对成膜透湿率的影响和交互作用。结果表明：随着蜂蜡添加量增加纳米α-Fe2O3添加量临界值降低且有效降低成膜透湿率，所以这2种材料之间存在明显的交互作用（P＜0.05）。回归优化的最优组蜂蜡添加量为0.739 g/100mL，纳米α-Fe2O3添加量为0.04 g/100mL时透湿率达到最低点，比对照组膜降低了73.76%（P＜0.05）。优化的膜材料具有明显的抑菌效果，在光催化条件下，能使大肠杆菌菌落总数下降1个数量级。
위유효적제고취을희순（polyvinyl alcohol，PVA）적성막후조습성능，해연구채용유화제취감유지화단감지복배유화봉사사기여PVA형성은정적유액。재PVA기막재료중첨가료봉사급납미α-Fe2O3，이용단인소시험학정료향응곡면시험적인소수평，종이사용향응면시험연구료량자지간대성막투습솔적영향화교호작용。결과표명：수착봉사첨가량증가납미α-Fe2O3첨가량림계치강저차유효강저성막투습솔，소이저2충재료지간존재명현적교호작용（P＜0.05）。회귀우화적최우조봉사첨가량위0.739 g/100mL，납미α-Fe2O3첨가량위0.04 g/100mL시투습솔체도최저점，비대조조막강저료73.76%（P＜0.05）。우화적막재료구유명현적억균효과，재광최화조건하，능사대장간균균락총수하강1개수량급。
Polyvinyl alcohol has been widely used as a packaging substrate, but its water resistance is poor. Improving the water resistance of polyvinyl alcohol is critical. In this study the major modification methods were to add nano-materials, fats or oil substances and crosslinking agents. Functional nanomaterials have small size, large surface area that combine the hydroxyl group with polyvinyl alcohol to reduce the hydrophilic. Beeswax is a composition material by fats and oils. It has higher melting point, acid corrosion, water-blocking performance characteristics. Furthermore it can form a stable emulsion, resulting in long shelf life, high solid content, good dispersion and other fine features. Beeswax is widely used in fruit and vegetable preservation, fruits and vegetables can reduce the water loss rate and respiration. In this experiment a stable emulsion with polyvinyl alcohol (PVA) was formed from hydrophobic of beeswax and the small surface area, high activity of nanosizedα-Fe2O3 to reduce film water vapor transmission rate of packing material of polyvinyl alcohol efficiently. By adding beeswax and nanosizedα-Fe2O3 to polyvinyl alcohol based composite coating material, the impacts of film-forming water vapor transmission rate and its interaction was studied through analyzing the response surface between the two experimental factors. The result showed that the increasing amount of beeswax and then nosizedα-Fe2O3 could reduce the water vapor transmission rate of polyvinyl alcohol composite material effectively. Therefore two materials have mutual impacts (P<0.05). The beeswax dosage was 0.739 g/100mL, and nanosizedα-Fe2O3 was 0.04 g/100mL based on the regression optimization. The water vapor transmission rate reached the lowest point, which was lower than the former Liquid paraffin-polyvinyl alcohol film 73.76% (P<0.05). Meanwhile, nanosizedα-Fe2O3 could be used as a new nano-material. Its narrow band gap generally was 2.2 eV, the maximum absorption wavelength was 560 nm that increases photocatalytic reaction in the utilization of light. The nanosizedα-Fe2O3was able to produce ?OH under the visible reaction which has strong oxidation ability to react with most organic degradation and bacterial until it was converted to CO2 and H2O. The optimized films have obvious antibiotic effect. In photocatalytic conditions, the total number of E.coli colonies can drop an order of magnitude. This study could be beneficial for developing better quality of preservation, and packaging film materials.